Three-dimensional memory device containing on-pitch drain select level structures and methods of making the same

ABSTRACT

A three-dimensional memory device includes an alternating stack of insulating layers and word-line-level electrically conductive layers located over a substrate, and a vertical layer stack located over the alternating stack, the vertical layer stack including an insulating cap layer, drain select electrodes, and a drain-select-level insulating layer. The drain select electrodes are laterally spaced apart from each other by drain-select-level isolation structures. Memory stack structures including a respective vertical semiconductor channel and a respective memory film vertically extend through the alternating stack and the vertical layer stack. Each of the vertical semiconductor channels includes a word-line-level semiconductor channel portion extending through the alternating stack, a connection channel portion contacting a top end of the word-line-level semiconductor channel, and a drain-select-level semiconductor channel portion vertically extending through the vertical layer stack.

RELATED APPLICATIONS

This application is a continuation-in-part application of a PCTapplication Serial No. PCT/US2019/20127 filed on Feb. 28, 2019, whichclaims the benefit of priority from U.S. Non-Provisional patentapplication Ser. Nos. 16/019,821 and 16/019,856 filed on Jun. 27, 2018,and the entire contents of which are incorporated herein by reference.

FIELD

The present disclosure relates generally to the field of semiconductordevices, and particular to a three-dimensional memory device includingon-pitch drain select level structures and methods of manufacturing thesame.

BACKGROUND

Three-dimensional vertical NAND strings having one bit per cell aredisclosed in an article by T. Endoh et al., titled “Novel Ultra HighDensity Memory With A Stacked-Surrounding Gate Transistor (S-SGT)Structured Cell,” IEDM Proc. (2001) 33-36.

SUMMARY

According to an aspect of the present disclosure, a three-dimensionalmemory device includes an alternating stack of insulating layers andword-line-level electrically conductive layers located over a substrate,and a vertical layer stack located over the alternating stack, thevertical layer stack including an insulating cap layer, drain selectelectrodes, and a drain-select-level insulating layer. The drain selectelectrodes are laterally spaced apart from each other bydrain-select-level isolation structures. Memory stack structuresincluding a respective vertical semiconductor channel and a respectivememory film vertically extend through the alternating stack and thevertical layer stack. Each of the vertical semiconductor channelsincludes a word-line-level semiconductor channel portion extendingthrough the alternating stack, a connection channel portion contacting atop end of the word-line-level semiconductor channel, and adrain-select-level semiconductor channel portion vertically extendingthrough the vertical layer stack.

According to another aspect of the present disclosure, a method offorming a three-dimensional memory device is provided, which comprises:forming an alternating stack of inter-word-line insulating layers andword-line-level sacrificial material layers over a substrate; formingmemory openings through the alternating stack; forming memory openingfill structures in the memory openings, wherein each of the memoryopening fill structures comprises a memory film, a word-line-levelsemiconductor channel portion, and a connection channel portion; forminga vertical layer stack including an insulating cap layer anddrain-select-level material layers over the alternating stack and thememory opening fill structures; forming drain select electrodes anddrain-select-level isolation structures by patterning or replacingportions of the vertical layer stack, wherein the drain selectelectrodes are laterally spaced apart from each other bydrain-select-level isolation structures; forming backside trenchesthrough the vertical layer stack and the alternating stack; andreplacing the word-line-level sacrificial material layers withword-line-level electrically conductive layers after formation of thedrain select electrodes and the drain-select-level insulating layer.

According to an aspect of the present disclosure, a three-dimensionalmemory device is provided, which comprises: an alternating stack ofinsulating layers and word-line-level electrically conductive layerslocated over a substrate; a plurality of multi-level drain selectelectrodes, each comprising a respective vertical connection portioncontacting and electrically connected to a respective set ofdrain-select-level electrically conductive layers that are verticallyspaced apart among one another and located over the alternating stack;memory stack structures comprising a respective vertical semiconductorchannel and a respective memory film, wherein each memory film has arespective sidewall that extends through the alternating stack and eachlevel of the multi-level drain select electrodes; and a firstdrain-select-level isolation structure overlying the alternating stack,laterally extending along a first horizontal direction and locatedbetween a neighboring pair of the multi-level drain select electrodes,and including a pair of sidewalls that include a respective set ofconcave vertical sidewall segments, wherein at least one multi-leveldrain select electrode of the plurality of the multi-level drain selectelectrodes contacts a sidewall of the first drain-select-level isolationstructure.

According to another aspect of the present disclosure, a method offorming a three-dimensional memory device is provided, which comprises:forming an alternating stack of insulating layers and word-line-levelspacer material layers over a substrate, wherein the word-line-levelspacer material layers are formed as, or are subsequently replaced with,word-line-level electrically conductive layers; formingdrain-select-level sacrificial material layers vertically spaced bydrain-select-level insulating layers over the alternating stack; formingdrain-select-level sacrificial line structures over the alternatingstack and through the drain-select-level sacrificial material layers;forming memory stack structures through the alternating stack, thedrain-select-level spacer material layers, and the drain-select-levelsacrificial line structures, wherein each memory stack structurecomprises a respective vertical semiconductor channel and a respectivememory film; forming drain-select-level backside recesses adjoined todrain-select-level isolation trenches by removing remaining portions ofthe drain-select-level sacrificial line structures and thedrain-select-level sacrificial material layers; and forming multi-leveldrain select electrodes comprising a respective vertical connectionportion contacting and electrically connected to a respective set ofdrain-select-level electrically conductive layers within volumes of thedrain-select-level backside recesses and the drain-select-levelisolation trenches.

According to yet another aspect of the present disclosure, athree-dimensional memory device is provided, which comprises: analternating stack of insulating layers and word-line-level electricallyconductive layers located over a substrate; multi-level drain selectelectrodes comprising a respective vertical connection portion adjoinedto a respective set of drain-select-level electrically conductive layersthat are vertically spaced apart among one another and located over thealternating stack; memory stack structures comprising a respectivevertical semiconductor channel laterally surrounded by a respectivememory film extending through the alternating stack , and laterallysurrounded by a respective gate dielectric extending through arespective one of the plurality of multi-level drain select electrodes;and a drain-select-level isolation structure overlying the alternatingstack, laterally extending along a first horizontal direction andlocated between a neighboring pair of the multi-level drain selectelectrodes, and including a pair of sidewalls that include a respectiveset of concave vertical sidewall segments, wherein each of themulti-level drain select electrodes contacts a sidewall of a subset ofthe gate dielectrics.

According to still another aspect of the present disclosure, a method offorming a three-dimensional memory device is provided, which comprises:forming an alternating stack of insulating layers and word-line-levelspacer material layers over a substrate, wherein the word-line-levelspacer material layers are formed as, or are subsequently replaced with,word-line-level electrically conductive layers; forming memory stackstructures through the alternating stack, wherein each memory stackstructure comprises a respective word-line-level semiconductor channelportion and a respective memory film; forming drain-select-levelsacrificial material layers spaced apart by drain-select-levelinsulating layers over the alternating stack; forming drain-select-levelsacrificial line structures through the drain-select-level sacrificialmaterial layers and the drain-select-level insulating layers; formingdrain-select-level backside recesses adjoined to drain-select-levelisolation trenches by removing portions of the drain-select-levelsacrificial line structures and the drain-select-level sacrificialmaterial layers; and forming multi-level drain select electrodescomprising a respective vertical connection portion adjoined torespective set of drain-select-level electrically conductive layerswithin volumes of the drain-select-level backside recesses and thedrain-select-level isolation trenches.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a vertical cross-sectional view of a first exemplary structureafter formation of at least one peripheral device and a semiconductormaterial layer according to a first embodiment of the presentdisclosure.

FIG. 2 is a vertical cross-sectional view of the first exemplarystructure after formation of an alternating stack of insulating layersand word-line-level sacrificial material layers according to the firstembodiment of the present disclosure.

FIG. 3A is a horizontal cross-sectional view of the first exemplarystructure after formation of drain-select-level insulating layers anddrain-select-level sacrificial material layers according to the firstembodiment of the present disclosure.

FIG. 3B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 3A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 3A.

FIG. 4 is a vertical cross-sectional view of the first exemplarystructure after formation of stepped terraces and a retro-steppeddielectric material portion according to the first embodiment of thepresent disclosure.

FIG. 5A is a horizontal cross-sectional view of the first exemplarystructure after formation of drain-select-level sacrificial linestructures according to the first embodiment of the present disclosure.

FIG. 5B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 5A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 5A.

FIG. 6A is a horizontal cross-sectional view of the first exemplarystructure after formation of memory openings according to the firstembodiment of the present disclosure.

FIG. 6B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 6A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 6A.

FIG. 7A is a horizontal cross-sectional view of the first exemplarystructure after formation of memory stack structures according to thefirst embodiment of the present disclosure.

FIG. 7B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 7A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 7A.

FIG. 8A is a horizontal cross-sectional view of the first exemplarystructure after formation of a backside trench according to the firstembodiment of the present disclosure.

FIG. 8B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 8A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 8A.

FIG. 9A is a horizontal cross-sectional view of the first exemplarystructure after formation of word-line-level backside recesses accordingto the first embodiment of the present disclosure.

FIG. 9B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 9A. The horizontal planeB-B′ is the plane of the horizontal cross-sectional view of FIG. 9A.

FIG. 10A is a horizontal cross-sectional view of the first exemplarystructure after formation of word-line-level electrically conductivelayers according to the first embodiment of the present disclosure.

FIG. 10B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 10A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.10A.

FIG. 11A is a horizontal cross-sectional view of the first exemplarystructure after formation of a dielectric divider structure in thebackside trench according to the first embodiment of the presentdisclosure.

FIG. 11B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 11A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.11A.

FIG. 12A is a horizontal cross-sectional view of the first exemplarystructure after removal of the drain-select-level sacrificial linestructures according to the first embodiment of the present disclosure.

FIG. 12B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 12A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.12A.

FIG. 13A is a horizontal cross-sectional view of the first exemplarystructure after removal of drain-select-level sacrificial materiallayers according to the first embodiment of the present disclosure.

FIG. 13B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 13A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.13A.

FIG. 14A is a horizontal cross-sectional view of the first exemplarystructure after formation of strips of a drain-select-level electricallyconductive layer according to the first embodiment of the presentdisclosure.

FIG. 14B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 14A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.14A.

FIG. 15A is a horizontal cross-sectional view of the first exemplarystructure after formation of a dielectric cap layer includingdrain-select-level isolation structures according to the firstembodiment of the present disclosure.

FIG. 15B is a vertical cross-sectional view of the first exemplarystructure along the vertical plane B-B′ of FIG. 15A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.15A.

FIG. 15C is a magnified view of a region around a drain-select-levelisolation structure in FIG. 15B.

FIG. 15D is a magnified view of a region around the dielectric dividerstructure of FIG. 15B.

FIG. 16A is a horizontal cross-sectional view of a second exemplarystructure after formation of an alternating stack of insulating layersand word-line-level sacrificial material layers, drain-select-levelinsulating layers, and drain-select-level sacrificial material layersaccording to a second embodiment of the present disclosure.

FIG. 16B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 16A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.16A.

FIG. 17A is a horizontal cross-sectional view of the second exemplarystructure after formation of drain-select-level sacrificial linestructures according to the second embodiment of the present disclosure.

FIG. 17B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 17A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.17A.

FIG. 18A is a horizontal cross-sectional view of the second exemplarystructure after formation of memory openings according to the secondembodiment of the present disclosure.

FIG. 18B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 18A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.18A.

FIG. 19A is a horizontal cross-sectional view of the second exemplarystructure after formation of memory stack structures according to thesecond embodiment of the present disclosure.

FIG. 19B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 19A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.19A.

FIG. 20A is a horizontal cross-sectional view of the second exemplarystructure after formation of a backside trench according to the secondembodiment of the present disclosure.

FIG. 20B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 20A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.20A.

FIG. 21A is a horizontal cross-sectional view of the second exemplarystructure after formation of word-line-level backside recesses and firstdrain-select-level backside recesses by removal of first portions of thedrain-select-level sacrificial material layers and according to thesecond embodiment of the present disclosure.

FIG. 21B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 21A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.21A.

FIG. 22A is a horizontal cross-sectional view of the second exemplarystructure after formation of word-line-level electrically conductivelayers and first segments of a drain-select-level electricallyconductive layer according to the second embodiment of the presentdisclosure.

FIG. 22B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 22A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.22A.

FIG. 23A is a horizontal cross-sectional view of the second exemplarystructure after formation of a dielectric divider structure in thebackside trench according to the second embodiment of the presentdisclosure.

FIG. 23B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 23A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.23A.

FIG. 24A is a horizontal cross-sectional view of the second exemplarystructure after removal of the drain-select-level sacrificial linestructures according to the second embodiment of the present disclosure.

FIG. 24B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 24A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.24A.

FIG. 25A is a horizontal cross-sectional view of the second exemplarystructure after removal of second portions of the drain-select-levelsacrificial material layers according to the second embodiment of thepresent disclosure.

FIG. 25B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 25A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.25A.

FIG. 26A is a horizontal cross-sectional view of the second exemplarystructure after formation of second segments of the drain-select-levelelectrically conductive layer according to the second embodiment of thepresent disclosure.

FIG. 26B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 26A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.26A.

FIG. 27A is a horizontal cross-sectional view of the second exemplarystructure after formation of a dielectric cap layer includingdrain-select-level isolation structures according to the secondembodiment of the present disclosure.

FIG. 27B is a vertical cross-sectional view of the second exemplarystructure along the vertical plane B-B′ of FIG. 27A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.27A.

FIG. 27C is a magnified view of a region around a seconddrain-select-level isolation structure in FIG. 27B.

FIG. 27D is a magnified view of another region around the seconddrain-select-level isolation structure of FIG. 27B.

FIG. 27E is a magnified view of a region around the dielectric dividerstructure of FIG. 27B.

FIG. 28A is a horizontal cross-sectional view of a third exemplarystructure after formation of an alternating stack of insulating layersand word-line-level sacrificial material layers and lower memory openingfill portions according to a third embodiment of the present disclosure.

FIG. 28B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 28A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.28A.

FIG. 29A is a horizontal cross-sectional view of a third exemplarystructure after formation of an insulating cap layer and a dielectricetch stop material layer according to a third embodiment of the presentdisclosure.

FIG. 29B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 29A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.29A.

FIG. 30A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level insulating layers anddrain-select-level sacrificial material layers according to the thirdembodiment of the present disclosure.

FIG. 30B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 30A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.30A.

FIG. 31A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level line trenches accordingto the third embodiment of the present disclosure.

FIG. 31B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 31A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.31A.

FIG. 32A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level sacrificial linestructures according to the third embodiment of the present disclosure.

FIG. 32B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 32A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.32A.

FIG. 33A is a horizontal cross-sectional view of the third exemplarystructure after formation of upper memory openings according to thethird embodiment of the present disclosure.

FIG. 33B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 33A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.33A.

FIG. 34A is a horizontal cross-sectional view of the third exemplarystructure after formation of a drain-select-level gate dielectric layerand a cover material layer according to the third embodiment of thepresent disclosure.

FIG. 34B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 34A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.34A.

FIG. 35A is a horizontal cross-sectional view of the third exemplarystructure after formation of a drain-select-level gate dielectric layerand cover material spacers according to the third embodiment of thepresent disclosure.

FIG. 35B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 35A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.35A.

FIG. 36A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level semiconductor channelportions, drain-select-level dielectric cores, and drain regionsaccording to the third embodiment of the present disclosure.

FIG. 36B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 36A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.36A.

FIG. 37A is a horizontal cross-sectional view of the third exemplarystructure after formation of a first dielectric cap layer according tothe third embodiment of the present disclosure.

FIG. 37B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 37A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.37A.

FIG. 38A is a horizontal cross-sectional view of the third exemplarystructure after formation of openings through the first dielectric caplayer according to the third embodiment of the present disclosure.

FIG. 38B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 38A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.38A.

FIG. 39A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level divider trenches anddrain-select-level isolation trenches according to the third embodimentof the present disclosure.

FIG. 39B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 38A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.38A.

FIG. 40A is a horizontal cross-sectional view of the third exemplarystructure after formation of drain-select-level backside recesses byremoval of the drain-select-level sacrificial material layers andaccording to the third embodiment of the present disclosure.

FIG. 40B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 40A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.40A.

FIG. 41A is a horizontal cross-sectional view of the third exemplarystructure after deposition of a conductive material in thedrain-select-level backside recesses according to the third embodimentof the present disclosure.

FIG. 41B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 41A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.41A.

FIG. 42A is a horizontal cross-sectional view of the third exemplarystructure after formation of segments of a drain-select-levelelectrically conductive layer by an anisotropic etch according to thethird embodiment of the present disclosure.

FIG. 42B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 42A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.42A.

FIG. 43A is a horizontal cross-sectional view of the third exemplarystructure after formation of a second dielectric cap layer includingdrain-select-level isolation structures according to the thirdembodiment of the present disclosure.

FIG. 43B is a vertical cross-sectional view of the third exemplarystructure along the vertical plane B-B′ of FIG. 43A. The horizontalplane B-B′ is the plane of the horizontal cross-sectional view of FIG.43A.

FIG. 43C is a vertical cross-sectional view of the third exemplarystructure along the vertical plane C-C′ of FIG. 43A.

FIG. 43D is a magnified view of a region of the vertical cross-sectionalview of FIG. 43B.

FIG. 43E is a vertical cross-sectional view of the third exemplarystructure along the vertical plane E-E′ of FIG. 43A.

FIG. 43F is a magnified view of a region of the vertical cross-sectionalview of FIG. 43C.

FIG. 44A is a vertical cross-sectional view of a configuration for thefirst, second, and third exemplary structures for providing electricalcontacts to various components therein.

FIG. 44B is a see-through top-down view of the exemplary structure ofFIG. 44A.

FIG. 45 is a vertical cross-sectional view of another configuration forthe first, second, and third exemplary structures for providingelectrical contacts to various components therein.

FIG. 46 is a vertical cross-sectional view of a fourth exemplarystructure after formation of an insulating cap layer anddrain-select-level material layers according to a fourth embodiment ofthe present disclosure.

FIG. 47 is a vertical cross-sectional view of the fourth exemplarystructure after formation of drain-select-level isolation structures anddrain-select-level insulating spacers according to the fourth embodimentof the present disclosure.

FIG. 48 is a vertical cross-sectional view of the fourth exemplarystructure after formation of drain-select-level memory openingsaccording to the fourth embodiment of the present disclosure.

FIG. 49 is a vertical cross-sectional view of the fourth exemplarystructure after formation of a gate dielectric layer and outerdrain-select-level semiconductor channel portions according to thefourth embodiment of the present disclosure.

FIG. 50 is a vertical cross-sectional view of the fourth exemplarystructure after formation of drain-select-level memory opening fillstructures and a first dielectric cap layer according to the fourthembodiment of the present disclosure.

FIG. 51 is a vertical cross-sectional view of the fourth exemplarystructure after formation of dielectric divider structures according tothe fourth embodiment of the present disclosure.

FIG. 52 is a vertical cross-sectional view of a fifth exemplarystructure after formation of an insulating cap layer anddrain-select-level material layers according to a fifth embodiment ofthe present disclosure.

FIG. 53 is a vertical cross-sectional view of the fifth exemplarystructure after formation of drain-select-level isolation structures anddrain-select-level insulating spacers according to the fifth embodimentof the present disclosure.

FIG. 54 is a vertical cross-sectional view of the fifth exemplarystructure after formation of drain-select-level memory openingsaccording to the fifth embodiment of the present disclosure.

FIG. 55 is a vertical cross-sectional view of the fifth exemplarystructure after formation of a sacrificial material liner according tothe fifth embodiment of the present disclosure.

FIG. 56 is a vertical cross-sectional view of the fifth exemplarystructure after formation of a sacrificial fill material layer accordingto the fifth embodiment of the present disclosure.

FIG. 57 is a vertical cross-sectional view of the fifth exemplarystructure after formation of sacrificial fill material portionsaccording to the fifth embodiment of the present disclosure.

FIG. 58 is a vertical cross-sectional view of the fifth exemplarystructure after formation of a sacrificial capping layer according tothe fifth embodiment of the present disclosure.

FIG. 59 is a vertical cross-sectional view of the fifth exemplarystructure after a first planarization process according to the fifthembodiment of the present disclosure.

FIG. 60 is a vertical cross-sectional view of the fifth exemplarystructure after removal of the drain-select-level sacrificial materiallayer according to the fifth embodiment of the present disclosure.

FIG. 61 is a vertical cross-sectional view of the fifth exemplarystructure after formation of drain select electrodes according to thefifth embodiment of the present disclosure.

FIG. 62 is a vertical cross-sectional view of the fifth exemplarystructure after formation of drain-select-level insulating layeraccording to the fifth embodiment of the present disclosure.

FIG. 63 is a vertical cross-sectional view of the fifth exemplarystructure after a second planarization process according to the fifthembodiment of the present disclosure.

FIG. 64 is a vertical cross-sectional view of the fifth exemplarystructure after removal of material portions from the drain-select-levelmemory openings according to the fifth embodiment of the presentdisclosure.

FIG. 65 is a vertical cross-sectional view of the fifth exemplarystructure after formation of gate dielectrics and outerdrain-select-level semiconductor channel portions according to the fifthembodiment of the present disclosure.

FIG. 66 is a vertical cross-sectional view of the fifth exemplarystructure after formation of drain-select-level memory opening fillstructures and a first dielectric cap layer according to the fifthembodiment of the present disclosure.

FIG. 67 is a vertical cross-sectional view of the fifth exemplarystructure after formation of dielectric divider structures according tothe fifth embodiment of the present disclosure.

DETAILED DESCRIPTION

As discussed above, the present disclosure is directed to athree-dimensional memory device including multi-level self-aligned drainselect level isolation structures and methods of manufacturing the same,the various aspects of which are described below. The multi-levelself-aligned drain select level isolation structures can provide acompact device layout and reduce a chip size without the need toallocate an extra dedicated area to the drain-select-level isolationstructure, as well as providing a simpler self aligned fabricationprocess. The embodiments of the disclosure can be employed to formvarious structures including a multilevel memory structure, non-limitingexamples of which include semiconductor devices such asthree-dimensional monolithic memory array devices comprising a pluralityof NAND memory strings.

The drawings are not drawn to scale. Multiple instances of an elementmay be duplicated where a single instance of the element is illustrated,unless absence of duplication of elements is expressly described orclearly indicated otherwise. Ordinals such as “first”, “second”, and“third” are employed merely to identify similar elements, and differentordinals may be employed across the specification and the claims of theinstant disclosure. The same reference numerals refer to the sameelement or similar element. Unless otherwise indicated, elements havingthe same reference numerals are presumed to have the same composition.Unless otherwise indicated, a “contact” between elements refers to adirect contact between elements that provides an edge or a surfaceshared by the elements. As used herein, a first element located “on” asecond element can be located on the exterior side of a surface of thesecond element or on the interior side of the second element. As usedherein, a first element is located “directly on” a second element ifthere exist a physical contact between a surface of the first elementand a surface of the second element.

As used herein, a “layer” refers to a material portion including aregion having a thickness. A layer may extend over the entirety of anunderlying or overlying structure, or may have an extent less than theextent of an underlying or overlying structure. Further, a layer may bea region of a homogeneous or inhomogeneous continuous structure that hasa thickness less than the thickness of the continuous structure. Forexample, a layer may be located between any pair of horizontal planesbetween, or at, a top surface and a bottom surface of the continuousstructure. A layer may extend horizontally, vertically, and/or along atapered surface. A substrate may be a layer, may include one or morelayers therein, or may have one or more layer thereupon, thereabove,and/or therebelow.

A monolithic three-dimensional memory array is one in which multiplememory levels are formed above a single substrate, such as asemiconductor wafer, with no intervening substrates. The term“monolithic” means that layers of each level of the array are directlydeposited on the layers of each underlying level of the array. Incontrast, two dimensional arrays may be formed separately and thenpackaged together to form a non-monolithic memory device. For example,non-monolithic stacked memories have been constructed by forming memorylevels on separate substrates and vertically stacking the memory levels,as described in U.S. Pat. No. 5,915,167 titled “Three-dimensionalStructure Memory.” The substrates may be thinned or removed from thememory levels before bonding, but as the memory levels are initiallyformed over separate substrates, such memories are not true monolithicthree-dimensional memory arrays. The various three-dimensional memorydevices of the present disclosure include a monolithic three-dimensionalNAND string memory device, and can be fabricated employing the variousembodiments described herein.

Referring to FIG. 1, a first exemplary structure according to anembodiment of the present disclosure is illustrated, which can beemployed, for example, to fabricate a device structure containingvertical NAND memory devices. The first exemplary structure includes asubstrate (9, 10), which can be a semiconductor substrate. The substratecan include a substrate semiconductor layer 9 and an optionalsemiconductor material layer 10.

The substrate semiconductor layer 9 maybe a semiconductor wafer or asemiconductor material layer, and can include at least one elementalsemiconductor material (e.g., single crystal silicon wafer or layer), atleast one III-V compound semiconductor material, at least one II-VIcompound semiconductor material, at least one organic semiconductormaterial, or other semiconductor materials known in the art. Thesubstrate can have a major surface 7, which can be, for example, atopmost surface of the substrate semiconductor layer 9. The majorsurface 7 can be a semiconductor surface. In one embodiment, the majorsurface 7 can be a single crystalline semiconductor surface, such as asingle crystalline semiconductor surface.

As used herein, a “semiconducting material” refers to a material havingelectrical conductivity in the range from 1.0×10⁻⁶ S/cm to 1.0×10⁵ S/cm.As used herein, a “semiconductor material” refers to a material havingelectrical conductivity in the range from 1.0×10⁻⁶ S/cm to 1.0×10⁵ S/cmin the absence of electrical dopants therein, and is capable ofproducing a doped material having electrical conductivity in a rangefrom 1.0 S/cm to 1.0×10⁵ S/cm upon suitable doping with an electricaldopant. As used herein, an “electrical dopant” refers to a p-type dopantthat adds a hole to a valence band within a band structure, or an n-typedopant that adds an electron to a conduction band within a bandstructure. As used herein, a “conductive material” refers to a materialhaving electrical conductivity greater than 1.0×10⁵ S/cm. As usedherein, an “insulator material” or a “dielectric material” refers to amaterial having electrical conductivity less than 1.0×10⁻⁶ S/cm. As usedherein, a “heavily doped semiconductor material” refers to asemiconductor material that is doped with electrical dopant at asufficiently high atomic concentration to become a conductive materialeither as formed as a crystalline material or if converted into acrystalline material through an anneal process (for example, from aninitial amorphous state), i.e., to have electrical conductivity greaterthan 1.0×10⁵ S/cm. A “doped semiconductor material” may be a heavilydoped semiconductor material, or may be a semiconductor material thatincludes electrical dopants (i.e., p-type dopants and/or n-type dopants)at a concentration that provides electrical conductivity in the rangefrom 1.0×10⁻⁶ S/cm to 1.0×10⁵ S/cm. An “intrinsic semiconductormaterial” refers to a semiconductor material that is not doped withelectrical dopants. Thus, a semiconductor material may be semiconductingor conductive, and may be an intrinsic semiconductor material or a dopedsemiconductor material. A doped semiconductor material can besemiconducting or conductive depending on the atomic concentration ofelectrical dopants therein. As used herein, a “metallic material” refersto a conductive material including at least one metallic elementtherein. All measurements for electrical conductivities are made at thestandard condition.

At least one semiconductor device 700 for a peripheral circuitry can beformed on a portion of the substrate semiconductor layer 9. The at leastone semiconductor device can include, for example, field effecttransistors. For example, at least one shallow trench isolationstructure 720 can be formed by etching portions of the substratesemiconductor layer 9 and depositing a dielectric material therein. Agate dielectric layer, at least one gate conductor layer, and a gatedielectric cap layer can be formed over the substrate semiconductorlayer 9, and can be subsequently patterned to form at least one gatestructure (750, 752, 754, 758), each of which can include a gatedielectric 750, a gate electrode (752, 754), and a gate dielectric cap758. The gate electrode (752, 754) may include a stack of a first gateelectrode portion 752 and a second gate electrode portion 754. At leastone gate spacer 756 can be formed around the at least one gate structure(750, 752, 754, 758) by depositing and anisotropically etching adielectric liner. Active regions 730 can be formed in upper portions ofthe substrate semiconductor layer 9, for example, by introducingelectrical dopants employing the at least one gate structure (750, 752,754, 758) as masking structures. Additional masks may be employed asneeded. The active region 730 can include source regions and drainregions of field effect transistors. A first dielectric liner 761 and asecond dielectric liner 762 can be optionally formed. Each of the firstand second dielectric liners (761, 762) can comprise a silicon oxidelayer, a silicon nitride layer, and/or a dielectric metal oxide layer.As used herein, silicon oxide includes silicon dioxide as well asnon-stoichiometric silicon oxides having more or less than two oxygenatoms for each silicon atoms. Silicon dioxide is preferred. In anillustrative example, the first dielectric liner 761 can be a siliconoxide layer, and the second dielectric liner 762 can be a siliconnitride layer. The least one semiconductor device for the peripheralcircuitry can contain a driver circuit for memory devices to besubsequently formed, which can include at least one NAND device.

A dielectric material such as silicon oxide can be deposited over the atleast one semiconductor device, and can be subsequently planarized toform a planarization dielectric layer 770. In one embodiment theplanarized top surface of the planarization dielectric layer 770 can becoplanar with a top surface of the dielectric liners (761, 762).Subsequently, the planarization dielectric layer 770 and the dielectricliners (761, 762) can be removed from an area to physically expose a topsurface of the substrate semiconductor layer 9. As used herein, asurface is “physically exposed” if the surface is in physical contactwith vacuum, or a gas phase material (such as air).

The optional semiconductor material layer 10, if present, can be formedon the top surface of the substrate semiconductor layer 9 prior to, orafter, formation of the at least one semiconductor device 700 bydeposition of a single crystalline semiconductor material, for example,by selective epitaxy. The deposited semiconductor material can be thesame as, or can be different from, the semiconductor material of thesubstrate semiconductor layer 9. The deposited semiconductor materialcan be any material that can be employed for the substrate semiconductorlayer 9 as described above. The single crystalline semiconductormaterial of the semiconductor material layer 10 can be in epitaxialalignment with the single crystalline structure of the substratesemiconductor layer 9. Portions of the deposited semiconductor materiallocated above the top surface of the planarization dielectric layer 770can be removed, for example, by chemical mechanical planarization (CMP).In this case, the semiconductor material layer 10 can have a top surfacethat is coplanar with the top surface of the planarization dielectriclayer 770.

The region (i.e., area) of the at least one semiconductor device 700 isherein referred to as a peripheral device region 200. The region inwhich a memory array is subsequently formed is herein referred to as amemory array region 100. A contact region 300 for subsequently formingstepped terraces of electrically conductive layers can be providedbetween the memory array region 100 and the peripheral device region200.

Referring to FIG. 2, a stack of an alternating plurality of firstmaterial layers (which can be insulating layers 32) and second materiallayers (which can be word-line-level sacrificial material layer 42) isformed over the top surface of the substrate (9, 10). As used herein, a“material layer” refers to a layer including a material throughout theentirety thereof. As used herein, an alternating plurality of firstelements and second elements refers to a structure in which instances ofthe first elements and instances of the second elements alternate. Asused herein, a “word-line-level” element refers to an element that isformed at, or adjacent to, any of the word line levels, i.e., at any ofthe levels at which a word line is to be subsequently formed.

Each instance of the first elements that is not an end element of thealternating plurality is adjoined by two instances of the secondelements on both sides, and each instance of the second elements that isnot an end element of the alternating plurality is adjoined by twoinstances of the first elements on both ends. The first elements mayhave the same thickness thereamongst, or may have different thicknesses.The second elements may have the same thickness thereamongst, or mayhave different thicknesses. The alternating plurality of first materiallayers and second material layers may begin with an instance of thefirst material layers or with an instance of the second material layers,and may end with an instance of the first material layers or with aninstance of the second material layers. In one embodiment, an instanceof the first elements and an instance of the second elements may form aunit that is repeated with periodicity within the alternating plurality.

Each first material layer includes a first material, and each secondmaterial layer includes a second material that is different from thefirst material. In one embodiment, each first material layer can be aninsulating layer 32, and each second material layer can be aword-line-level sacrificial material layer. The insulating layers 32 areformed between word line levels, i.e., levels at which word lines are tobe subsequently formed. As such, the insulating layers 32 are alsoreferred to as word-line-level insulating layers 32. In this case, thestack can include an alternating plurality of insulating layers 32 andword-line-level sacrificial material layers 42, and constitutes aprototype stack of alternating layers comprising insulating layers 32and word-line-level sacrificial material layers 42. As used herein, a“prototype” structure or an “in-process” structure refers to a transientstructure that is subsequently modified in the shape or composition ofat least one component therein.

The stack of the alternating plurality is herein referred to as analternating stack (32, 42). In one embodiment, the alternating stack(32, 42) can include insulating layers 32 composed of the firstmaterial, and word-line-level sacrificial material layers 42 composed ofa second material different from that of insulating layers 32. The firstmaterial of the insulating layers 32 can be at least one insulatingmaterial. As such, each insulating layer 32 can be an insulatingmaterial layer. Insulating materials that can be employed for theinsulating layers 32 include, but are not limited to, silicon oxide(including doped or undoped silicate glass), silicon nitride, siliconoxynitride, organosilicate glass (OS G), spin-on dielectric materials,dielectric metal oxides that are commonly known as high dielectricconstant (high-k) dielectric oxides (e.g., aluminum oxide, hafniumoxide, etc.) and silicates thereof, dielectric metal oxynitrides andsilicates thereof, and organic insulating materials. In one embodiment,the first material of the insulating layers 32 can be silicon oxide. Theinsulating layers 32 include a topmost insulating layer 32T andinter-word-line insulating layers 32W located between a respectivevertically neighboring pair of word-line-level sacrificial materiallayers 42.

The second material of the word-line-level sacrificial material layers42 is a sacrificial material that can be removed selective to the firstmaterial of the insulating layers 32. As used herein, a removal of afirst material is “selective to” a second material if the removalprocess removes the first material at a rate that is at least twice therate of removal of the second material. The ratio of the rate of removalof the first material to the rate of removal of the second material isherein referred to as a “selectivity” of the removal process for thefirst material with respect to the second material.

The word-line-level sacrificial material layers 42 may comprise aninsulating material, a semiconductor material, or a conductive material.The second material of the word-line-level sacrificial material layers42 can be subsequently replaced with electrically conductive electrodeswhich can function, for example, as control gate electrodes of avertical NAND device. Non-limiting examples of the second materialinclude silicon nitride, an amorphous semiconductor material (such asamorphous silicon), and a polycrystalline semiconductor material (suchas polysilicon). In one embodiment, the word-line-level sacrificialmaterial layers 42 can be word-line-level spacer material layers thatcomprise silicon nitride or a semiconductor material including at leastone of silicon and germanium.

In one embodiment, the insulating layers 32 can include silicon oxide,and word-line-level sacrificial material layers can include siliconnitride word-line-level sacrificial material layers. The first materialof the insulating layers 32 can be deposited, for example, by chemicalvapor deposition (CVD). For example, if silicon oxide is employed forthe insulating layers 32, tetraethyl orthosilicate (TEOS) can beemployed as the precursor material for the CVD process. The secondmaterial of the word-line-level sacrificial material layers 42 can beformed, for example, CVD or atomic layer deposition (ALD).

The word-line-level sacrificial material layers 42 can be suitablypatterned so that conductive material portions to be subsequently formedby replacement of the word-line-level sacrificial material layers 42 canfunction as electrically conductive electrodes, such as the control gateelectrodes of the monolithic three-dimensional NAND string memorydevices to be subsequently formed. The word-line-level sacrificialmaterial layers 42 may comprise a portion having a strip shape extendingsubstantially parallel to the major surface 7 of the substrate.

The thicknesses of the insulating layers 32 and the word-line-levelsacrificial material layers 42 can be in a range from 20 nm to 50 nm,although lesser and greater thicknesses can be employed for eachinsulating layer 32 and for each word-line-level sacrificial materiallayer 42. The topmost insulating layer 32T can have a thickness in arange from 40 nm to 200 nm, although lesser and greater thicknesses canalso be employed. The number of repetitions of the pairs of aninsulating layer 32 and a word-line-level sacrificial material layer(e.g., a control gate electrode or a word-line-level sacrificialmaterial layer) 42 can be in a range from 2 to 1,024, and typically from8 to 256, although a greater number of repetitions can also be employed.The top and bottom gate electrodes in the stack may function as theselect gate electrodes. In one embodiment, each word-line-levelsacrificial material layer 42 in the alternating stack (32, 42) can havea uniform thickness that is substantially invariant within eachrespective word-line-level sacrificial material layer 42. The topmostlayer among the insulating layers 32 is herein referred to as a topmostinsulating layer 32T. The alternating stack (32, 42) may terminate withthe topmost insulating layer 32.

While the present disclosure is described employing an embodiment inwhich the word-line-level spacer material layers are word-line-levelsacrificial material layers 42 that are subsequently replaced withelectrically conductive layers, embodiments are expressly contemplatedherein in which the word-line-level sacrificial material layers areformed as electrically conductive layers. In this case, steps forreplacing the word-line-level spacer material layers with electricallyconductive layers can be omitted.

Referring to FIGS. 3A and 3B, drain-select-level sacrificial materiallayers 142 and drain-select-level insulating layers 132 can be formedover the alternating stack (32, 42). As used herein, a“drain-select-level” element refers to an element that is formed at, oradjacent to, any of the drain select levels, i.e., at any of the levelsat which a drain select gate electrode is to be subsequently formed. Thetopmost layer among the drain-select-level insulating layers 132 isherein referred to as a topmost drain-select-level insulating layer132T. The drain-select-level sacrificial material layers 142 arevertically spaced by the drain-select-level insulating layers 132. Inone embodiment, the drain-select-level insulating layers 132 can includethe same material as the insulating layers 32, and thedrain-select-level sacrificial material layers 142 can include the samematerial as the word-line-level sacrificial material layers 42. In oneembodiment, the drain-select-level insulating layers 132 and theinsulating layers 32 can include undoped silicate glass or a dopedsilicate glass, and the drain-select-level sacrificial material layers142 and the word-line-level sacrificial material layers 42 can includesilicon nitride. The thickness of each of the drain-select-levelinsulating layers 132 and the drain-select-level sacrificial materiallayers 142 can be in a range from 20 nm to 50 nm, although lesser andgreater thicknesses can also be employed. The topmost drain-select-levelinsulating layer 132T can have a thickness in a range from 40 nm to 200nm, although lesser and greater thicknesses can also be employed. Theset of all drain-select-level insulating layers 132 and alldrain-select-level sacrificial material layers 142 is herein referred toas a drain-select-level alternating stack (132, 142).

Referring to FIG. 4, a stepped cavity can be formed within the contactregion 300 which is located between the memory array region 100 and theperipheral device region 200 containing the at least one semiconductordevice for the peripheral circuitry. The stepped cavity can have variousstepped surfaces such that the horizontal cross-sectional shape of thestepped cavity changes in steps as a function of the vertical distancefrom the top surface of the substrate (9, 10). In one embodiment, thestepped cavity can be formed by repetitively performing a set ofprocessing steps. The set of processing steps can include, for example,an etch process of a first type that vertically increases the depth of acavity by one or more levels, and an etch process of a second type thatlaterally expands the area to be vertically etched in a subsequent etchprocess of the first type. As used herein, a “level” of a structureincluding alternating plurality is defined as the relative position of apair of a first material layer and a second material layer within thestructure.

Stepped surfaces are formed at a peripheral portion of the alternatingstack (32, 42) through formation of the stepped cavity. As used herein,“stepped surfaces” refer to a set of surfaces that include at least twohorizontal surfaces and at least two vertical surfaces such that eachhorizontal surface is adjoined to a first vertical surface that extendsupward from a first edge of the horizontal surface, and is adjoined to asecond vertical surface that extends downward from a second edge of thehorizontal surface. A “stepped cavity” refers to a cavity having steppedsurfaces.

A terrace region is formed by patterning the drain-select-levelalternating stack (132, 142) and the alternating stack (32, 42). Eachword-line-level sacrificial material layer 42 other than a topmostword-line-level sacrificial material layer 42 within the alternatingstack (32, 42) laterally extends farther than any overlyingword-line-level sacrificial material layer 42 within the alternatingstack (32, 42). Each drain-select-level sacrificial material layer 142can have a lateral extent less than the topmost word-line-levelsacrificial material layer 42. The terrace region includes steppedsurfaces of the alternating stack (32, 42) that continuously extend froma bottommost layer within the alternating stack (32, 42) to a topmostlayer within the alternating stack (32, 42).

A retro-stepped dielectric material portion 65 (i.e., an insulating fillmaterial portion) can be formed in the stepped cavity by deposition of adielectric material therein. For example, a dielectric material such assilicon oxide can be deposited in the stepped cavity. Excess portions ofthe deposited dielectric material can be removed from above the topmostsurface of the alternating stack (32, 42), for example, by chemicalmechanical planarization (CMP). The remaining portion of the depositeddielectric material filling the stepped cavity constitutes theretro-stepped dielectric material portion 65. As used herein, a“retro-stepped” element refers to an element that has stepped surfacesand a horizontal cross-sectional area that increases monotonically as afunction of a vertical distance from a top surface of a substrate onwhich the element is present. If silicon oxide is employed for theretro-stepped dielectric material portion 65, the silicon oxide of theretro-stepped dielectric material portion 65 may, or may not, be dopedwith dopants such as B, P, and/or F.

Referring to FIGS. 5A and 5B, drain-select-level sacrificial linestructures 73 extending along a first horizontal direction hd1 can beformed. For example, line trenches laterally extending along the firsthorizontal direction hd1 and having a uniform width along a secondhorizontal direction hd2 that is perpendicular to the first horizontaldirection hd1 can be formed through each of the drain-select-levelsacrificial material layers 142. The line trenches can be filled with asacrificial material such as amorphous silicon, polysilicon, asilicon-germanium alloy, a silicon-containing polymer, amorphous carbon,diamond-like carbon, or organosilicate glass. Excess portions of thesacrificial material can be removed from above the topmostdrain-select-level insulating layer 132T by a planarization process thatemploys a recess etch and/or chemical mechanical planarization (CMP).The remaining portions of the sacrificial material constitute thedrain-select-level sacrificial line structures 73. The width of eachdrain-select-level sacrificial line structure 73 is less than aninter-row pitch of rows of memory openings to be subsequently formed.

Referring to FIGS. 6A and 6B, multiple parallel rows of memory openings49 are formed through the drain-select-level alternating stack (132,142), the alternating stack (32 42), and the drain-select-levelsacrificial line structures 73. Memory openings 49 within each row arearranged along the first horizontal direction hd1, which is parallel tothe lengthwise direction of the drain-select-level sacrificial linestructures 73. The multiple parallel rows are laterally spaced apartalong the second horizontal direction hd2. A pair of rows (R1, R2) ofmemory openings 49 can pass through each drain-select-level sacrificialline structure 73 within a first subset S1 of the drain-select-levelsacrificial line structures 73. A respective row R1 or R2 of memoryopenings 49 passes through each lengthwise sidewall of eachdrain-select-level sacrificial line structure 73 within the first subsetS1 of the drain-select-level sacrificial line structures 73. A singlerow R3 of memory openings 49 can pass through each drain-select-levelsacrificial line structure 73 within a second subset S2 of thedrain-select-level sacrificial line structures 73. A row R3 of memoryopenings 49 passes through one lengthwise sidewall of eachdrain-select-level sacrificial line structure 73 within the secondsubset of the drain-select-level sacrificial line structures 73, whilethe memory openings 49 do not pass through the opposite lengthwisesidewall of each drain-select-level sacrificial line structure 73 withinthe second subset S2 of the drain-select-level sacrificial linestructures 73. In one embodiment, an area 79A laterally bounded by apair of drain-select-level sacrificial line structures 73 within thesecond subset S2 of the drain-select-level sacrificial line structures73 can be free of memory openings 49, and can be subsequently employedto form a backside trench therethrough.

Segments of each of the drain-select-level sacrificial line structures73 are etched during formation of the multiple parallel rows of openings49. Each of the drain-select-level sacrificial line structures 73 withinthe first subset 51 of the drain-select-level sacrificial linestructures 73 can be patterned to include a respective pair of laterallyalternating sequences of planar vertical sidewall segments 73P andconcave vertical sidewall segments 73C during formation of the memoryopenings 49. Each of the drain-select-level sacrificial line structures73 within the second subset S2 of the drain-select-level sacrificialline structures 73 can be patterned to include one laterally alternatingsequence of planar vertical sidewall segments 73P and concave verticalsidewall segments 73C during formation of the memory openings 49. Asused herein, a “planar vertical sidewall segment” refers to a segment ofa vertical sidewall that has a horizontal cross-sectional shape having azero curvature. As used herein, a “concave vertical sidewall segment”refers to a segment of a vertical sidewall that has a horizontalcross-sections shape having a concave shape. The memory openings canextend to a top surface of the semiconductor material layer 10.

Additional openings can be formed in the contact region 300 concurrentlywith formation of the memory openings 49. Such additional openings areherein referred to as support openings, which can be employed to formsupport pillar structures therein.

Referring to FIGS. 7A and 7B, memory opening fill structures 58 areformed in the memory openings 49. Each memory opening fill structure 58can include, for example, a memory film 50, a vertical semiconductorchannel 60, an optional dielectric core 62, a drain region 63, and adielectric memory opening cap portion 64. Each memory film 50 caninclude a blocking dielectric 52, a charge storage layer 54, and atunneling dielectric 56. The blocking dielectric 52 includes adielectric material such as silicon oxide and/or a dielectric metaloxide (such as aluminum oxide). The charge storage layer 54 includes adielectric charge storage material such as silicon nitride. Thetunneling dielectric 56 includes a tunneling dielectric material such asan ONO stack.

The vertical semiconductor channel 60 may include a single semiconductormaterial layer or a plurality of semiconductor material layers, such aspolysilicon. The vertical semiconductor channel 60 can contact thesemiconductor material layer 10 underlying the alternating stack (32,42) through an opening in the memory film 50, which may be formed by ananisotropic etch that removes horizontal portions of conformallydeposited dielectric material layers that include the various componentlayers within the memory film 50. Optionally, a cover material liner maybe employed to protect the memory film 50 during the anisotropic etchprocess that forms the opening at the bottom of each memory film 50. Thecover material liner may be a sacrificial material liner that issubsequently removed, or a semiconductor material liner that isincorporated into the vertical semiconductor channel 60. The verticalsemiconductor channel 60 can have a doping of a first conductivity type,which may be p-type or n-type. The atomic concentration of dopants ofthe first conductivity type in the vertical semiconductor channel 60 maybe in a range from 1.0×10¹⁴/cm³ to 1.0×10¹⁸/cm³, although lesser andgreater atomic concentrations can also be employed.

In case the memory opening has a cylindrical cavity therein afterformation of the vertical semiconductor channel 60, a dielectricmaterial such as silicon oxide can be deposited in the cylindricalcavity to form a dielectric core 62. A drain region 63 including asemiconductor material (e.g., polysilicon or amorphous silicon) having adoping of a second conductivity type can be formed above the horizontalplane including the top surface of the topmost drain-select-levelsacrificial material layer 142 and on an upper end of the verticalsemiconductor channel 60. The second conductivity type is the oppositeof the first conductivity type. The atomic concentration of dopants ofthe second conductivity type within the drain region 63 can be in arange from 5.0×10¹⁹/cm³ to 2.0×10²¹/cm³, although lesser and greateratomic concentrations can also be employed. A dielectric memory openingcap portion 64 is formed on top of the drain region 63. The top surfaceof the dielectric memory opening cap portion 64 can be coplanar with thetop surface of the topmost drain-select-level insulating cap layer 132T.

Each contiguous combination of a memory film 50 and a verticalsemiconductor channel 60 constitutes a memory stack structure 55. Thememory stack structures 55 are formed in the multiple parallel rows ofmemory openings 49 through the alternating stack, the drain-select-levelalternating stack (132, 142), and the drain-select-level sacrificialline structures 73.

Referring to FIGS. 8A and 8B, a photoresist layer (not shown) can beapplied over the topmost drain-select-level insulating layer 132T, andcan be lithographically patterned to form openings in areas 79A betweena pair of drain-select-level sacrificial line structures 73 within thesecond subset S2 of the drain-select-level sacrificial line structures73. The pattern in the photoresist layer can be transferred through thedrain-select-level alternating stack (132, 142) and the alternatingstack (32, 42) employing an anisotropic etch to form backside trenches79. Each backside trench 79 can vertically extend from the top surfaceof the topmost drain-select-level insulating layer 132T at least to thetop surface of the substrate (9, 10), and laterally extend through thememory array region 100 and the contact region 300.

In one embodiment, the backside trenches 79 can laterally extend alongthe first horizontal direction hd1 and can be laterally spaced apartamong one another along the second horizontal direction hd2 that isperpendicular to the first horizontal direction. The memory stackstructures 55 (included in the memory opening fill structures 58) can bearranged in rows that extend along the first horizontal direction hd1.Each backside trench 79 can have a uniform width that is invariant alongthe lengthwise direction (i.e., along the first horizontal directionhd1). Multiple rows of memory stack structures 55 can be located betweena neighboring pair of a backside trench 79 and a drain-select-levelsacrificial line structure 73, or between a neighboring pair ofdrain-select-level sacrificial line structures 73. In one embodiment,the backside trenches 79 can include a source contact opening in which asource contact via structure can be subsequently formed. The photoresistlayer can be removed, for example, by ashing. Sidewalls of thedrain-select-level sacrificial line structures 73 within the secondsubset of the drain-select-level sacrificial line structures 73 can bephysically exposed to the backside trenches 79.

Referring to FIGS. 9A and 9B, word-line-level backside recesses 43 canbe formed by isotropically etching the word-line-level sacrificialmaterial layers 42 employing an isotropic etchant. The etchant canselectively etch the second material of the word-line-level sacrificialmaterial layers 42 with respect to the first material of the insulatinglayers 32. The etchant can be introduced into the backside trenches 79,for example, employing an etch process while remaining portions of thedrain-select-level sacrificial line structures 73 protect thedrain-select-level sacrificial material layers 142. Specifically, thecombination of the topmost drain-select-level insulating layer 132T andthe drain-select-level sacrificial line structures 73 prevent theetchant from accessing the drain-select-level sacrificial materiallayers 142.

Word-line-level backside recesses 43 are formed in volumes from whichthe word-line-level sacrificial material layers 42 are removed.Likewise, one or more source-select-level recesses (not shown) areformed below the word-line-level backside recesses 43. The removal ofthe second material of the word-line-level sacrificial material layers42 can be selective to the first material of the insulating layers 32,the material of the retro-stepped dielectric material portion 65, thesemiconductor material of the semiconductor material layer 10, and thematerial of the outermost layer of the memory films 50. In oneembodiment, the word-line-level sacrificial material layers 42 caninclude silicon nitride, and the materials of the insulating layers 32and the retro-stepped dielectric material portion 65 can be selectedfrom silicon oxide and dielectric metal oxides.

The etch process that removes the second material selective to the firstmaterial and the outermost layer of the memory films 50 can be a wetetch process employing a wet etch solution, or can be a gas phase (dry)etch process in which the etchant is introduced in a vapor phase intothe backside trenches 79. For example, if the word-line-levelsacrificial material layers 42 include silicon nitride, the etch processcan be a wet etch process in which the first exemplary structure isimmersed within a wet etch tank including phosphoric acid, which etchessilicon nitride selective to silicon oxide, silicon, and various othermaterials employed in the art. The memory opening fill structures 58,support pillar structures (not shown) formed in the support openings inthe contact region 300, and the retro-stepped dielectric materialportion 65 provide structural support while the word-line-level backsiderecesses 43 are present within volumes previously occupied by theword-line-level sacrificial material layers 42.

Each word-line-level backside recess 43 can be a laterally extendingcavity having a lateral dimension that is greater than the verticalextent of the cavity. In other words, the lateral dimension of eachword-line-level backside recess 43 can be greater than the height of theword-line-level backside recess 43. A plurality of word-line-levelbackside recesses 43 can be formed in the volumes from which the secondmaterial of the word-line-level sacrificial material layers 42 isremoved. The memory openings in which the memory stack structures 55 areformed are herein referred to as front side openings or front sidecavities in contrast with the word-line-level backside recesses 43. Inone embodiment, the memory array region 100 comprises an array ofmonolithic three-dimensional NAND strings having a plurality of devicelevels disposed above the substrate (9, 10). In this case, eachword-line-level backside recess 43 can define a space for receiving arespective word line of the array of monolithic three-dimensional NANDstrings.

Each of the plurality of word-line-level backside recesses 43 can extendsubstantially parallel to the top surface of the substrate (9, 10), suchas surface 7 of the substrate semiconductor layer 9. A word-line-levelbackside recess 43 can be vertically bounded by a top surface of anunderlying insulating layer 32 and a bottom surface of an overlyinginsulating layer 32. In one embodiment, each word-line-level backsiderecess 43 can have a uniform height throughout.

Referring to FIGS. 10A and 10B, a backside blocking dielectric layer(not expressly illustrated) can be optionally formed at peripheralportions of the word-line-level backside recesses 43 and the backsidetrenches 79 by a conformal deposition process. The backside blockingdielectric layer, if present, comprises a dielectric material thatfunctions as a control gate dielectric for the control gates to besubsequently formed in the word-line-level backside recesses 43. In casethe blocking dielectric layer 52 is present within each memory opening,the backside blocking dielectric layer is optional. In case the blockingdielectric layer 52 is omitted, the backside blocking dielectric layeris present. For example, the backside blocking dielectric layer caninclude a dielectric metal oxide such as aluminum oxide.

At least one conductive material can be conformally deposited in theword-line-level backside recesses 43 and in the one or moresource-select-level recesses (not shown) located below theword-line-level backside recesses 43. For example, a combination of ametallic barrier layer and a metal fill material can be deposited in theword-line-level backside recesses 43. The metallic barrier layerincludes an electrically conductive metallic material that can functionas a diffusion barrier layer and/or adhesion promotion layer for ametallic fill material to be subsequently deposited. The metallicbarrier layer can include a conductive metallic nitride material such asTiN, TaN, WN, or a stack thereof. In one embodiment, the metallicbarrier layer can be deposited by a conformal deposition process such aschemical vapor deposition (CVD) or atomic layer deposition (ALD). Thethickness of the metallic barrier layer can be in a range from 2 nm to 8nm, such as from 3 nm to 6 nm, although lesser and greater thicknessescan also be employed. In one embodiment, the metallic barrier layer canconsist essentially of a conductive metal nitride such as TiN.

The metal fill material can be deposited on the metallic barrier layerto fill remaining volumes of the word-line-level backside recesses 43.The metallic fill material can be deposited by a conformal depositionmethod, which can be, for example, chemical vapor deposition (CVD),atomic layer deposition (ALD), electroless plating, electroplating, or acombination thereof. In one embodiment, the metallic fill material canconsist essentially of at least one elemental metal. The at least oneelemental metal of the metallic fill material layer can be selected, forexample, from tungsten, cobalt, ruthenium, titanium, and tantalum. Inone embodiment, the metallic fill material layer can consist essentiallyof a single elemental metal.

Excess portions of the deposited metallic material in the backsidetrenches 79 and over the topmost drain-select-level insulating layer132T can be etched back, for example, by an isotropic wet etch, ananisotropic dry etch, or a combination thereof. Remaining portions ofthe deposited metallic material in the word-line-level backside recesses43 comprise word-line-level electrically conductive layers 46 (e.g.,word lines/control gate electrodes). Remaining portions of the depositedmetallic material in the one or more source-select-level recesses (notshown) comprise source-select-level conductive layers (e.g., sourceselect gate electrodes). Each word-line-level electrically conductivelayer 46 can be a conductive line structure. Thus, the word-line-levelsacrificial material layers 42 can be replaced with the word-line-levelelectrically conductive layers 46. Each word-line-level electricallyconductive layer 46 can include a portion of the metallic barrier layerand a portion of the metallic fill material.

Referring to FIGS. 11A and 11B, a dielectric material such as undopedsilicate glass or doped silicate glass can be deposited in the backsidetrenches 79. Excess portions of the deposited dielectric material can beremoved from above the horizontal plane including the top surface of thetopmost drain-select-level insulating layer 132T by a planarizationprocess such as a recess etch process or a chemical mechanicalplanarization process. Each remaining portion of the dielectric materialin the backside trenches comprises a dielectric divider structure 76,which can be a dielectric wall structure laterally extending along thefirst horizontal direction hd1 and vertically extending through analternating stack of the insulating layers 32 and the word-line-levelelectrically conductive layers 46 and through the alternating stack ofthe drain-select-level insulating layers 132 and the drain-select-levelsacrificial material layers 142. In one embodiment, the dielectricdivider structure 76 can be formed in a tubular shape, for example, bydeposition of a conformal dielectric material liner and an anisotropicetch process, and a conductive contact via structure (e.g., sourceelectrode or local interconnect 81 shown in FIG. 44A) is may be formedwithin a cavity in the tubular dielectric divider structure 76. In thiscase, a source region (element 61 shown in FIG. 44A) may be formed in anupper portion of the semiconductor material layer 10 underlying thebackside trench 79 and in contact with the conductive contact viastructure.

In one embodiment, each dielectric divider structure 76 includes a pairof lengthwise sidewalls that laterally extend along the first horizontaldirection hd1 and vertically extends through the alternating stack ofthe insulating layers 32 and the word-line-level electrically conductivelayers 46 and through each level of the drain-select level sacrificialmaterial layers 142.

Referring to FIGS. 12A and 12B, remaining portions of thedrain-select-level sacrificial line structures 73 can be subsequentlyremoved by a selective etch process that etches the material of thedrain-select-level sacrificial line structures 73 selective to thematerials of the dielectric memory opening cap portions 64, the topmostdrain-select-level insulating layer 132T, and the dielectric dividerstructures 76. For example, if the drain-select-level sacrificial linestructures 73 include amorphous silicon or polysilicon, a wet etchprocess employing hot trimethyl-2 hydroxyethyl ammonium hydroxide (“hotTMY”), tetramethyl ammonium hydroxide (TMAH), or ammonium hydroxide canbe employed to remove the drain-select-level sacrificial line structures73. Drain-select-level isolation trenches 71 can be formed in thevolumes from which the drain-select-level sacrificial line structures 73are removed. Thus, at this step in the process, the drain-select-levelsacrificial line structures 73 are completely removed.

Referring to FIGS. 13A and 13B, the drain-select-level sacrificialmaterial layers 142 are removed by a selective etch process that etchesthe material of the drain-select-level sacrificial material layers 142without etching the materials of the drain-select-level insulatinglayers 132 or the dielectric divider structures 76 by providing anetchant through the drain-select-level isolation trenches 71. Forexample, if the drain-select-level sacrificial material layers 142include silicon nitride and if the drain-select-level insulating layers132 or the dielectric divider structures 76 include silicon oxidematerials, the drain-select-level sacrificial material layers 142 can beremoved by a wet etch process employing hot phosphoric acid.Drain-select-level backside recesses 143 are formed in volumes fromwhich the drain-select-level sacrificial material layers 142 are removedthrough the drain-select-level isolation trenches 71.

Referring to FIGS. 14A and 14B, at least one metallic fill material isdeposited in the drain-select-level backside recesses 143 through thedrain-select-level isolation trenches 71, and peripheral portions of thedrain-select-level isolation trenches 71 by at least one conformaldeposition process. The at least one metallic fill material can include,for example, a metallic barrier liner including a conducive metalnitride material (such as TiN, TaN, or WN) and/or a metal fill materialsuch as tungsten, cobalt, molybdenum, and/or ruthenium. Thethickness(es) of the at least one metallic material can be selected suchthat the drain-select-level isolation trenches 71 are not completelyfilled with the at least one metallic fill material.

An anisotropic etch process is performed to remove horizontal portionsof the at least one metallic fill material from above the topmostdrain-select-level insulating layer 132T and from the bottom portion ofeach drain-select-level isolation trench 71. Each remaining portion ofthe at least one metallic fill material filling the drain-select-levelbackside recesses 143 constitute a strip of a drain-select-levelelectrically conductive layer 446H. Each remaining vertical portion ofthe at least one metallic fill material adjoined to a respective set ofdrain-select-level electrically conductive layers 446H constitutes avertical connection portion 446V. Each contiguous set ofdrain-select-level electrically conductive layers 446H and at least onevertical connection portion 446V which contacts and electricallyconnects the drain-select-level electrically conductive layers 446H toeach other constitute a drain-select-level electrode 446. In oneembodiment, a drain-select-level electrode 446 can include two verticalconnection portions 446V adjoined to two or more, such as three to sixdrain-select-level electrically conductive layers 446H.

A drain-select-level cavity 71′ that generally extends along the firsthorizontal direction hd1 can be located within each drain-select-levelisolation trench 71. A vertical metallic spacer 446′ can be formed oneach sidewall of the dielectric divider structures 76 that laterallyextend along the first horizontal direction hd1. Each drain-select-levelelectrically conductive layer 446H can be formed in multiple portionsthat are laterally spaced apart by the drain-select-level cavities 71′.Each drain-select-level electrically conductive layer 446H can be formedin volumes from which a respective drain-select-level sacrificialmaterial layer 142 is removed.

Referring to FIGS. 15A-15D, a dielectric cap layer 80 is formed bydepositing a dielectric material such as a silicon oxide material overthe topmost drain-select-level insulating layer 132T and in thedrain-select-level cavities 71′. Each portion of the dielectric caplayer 80 that fills a respective drain-select-level cavity 71′ is hereinreferred to as a drain-select-level isolation structure 80S. Thus, thedrain-select-level isolation structures 80S are formed within volumesfrom which the remaining portions of the drain-select-level sacrificialline structures 73 are removed.

As shown in FIG. 15C, each drain-select-level electrode 446 can includea first metallic barrier liner 446A that continuously extends from abottommost surface of the drain-select-level electrode 446 to a topmostsurface of the drain-select-level electrode 446. For example, the firstmetallic barrier liner 446A of each drain-select-level electrode 446 cancontinuously extend from a bottom surface of a vertical connectionportion 446V that contacts a recessed horizontal surface of the topmostinsulating layer 32T to a top surface of the vertical connection portion446V that contacts a stepped surface of a drain-select-level isolationstructure 80S.

Each drain-select-level electrode 446 can include a first metallic fillmaterial portion 446B that consists essentially of an elemental metal oran intermetallic alloy. The first metallic fill material portion 446Bcan contact a non-vertical surface NVS (such as a horizontal steppedsurface) of a drain-select-level isolation structure 80S, for example,at the topmost surface located at a top end of the vertical connectionportion 446V. The non-vertical surface NVS adjoins a bottom edge of afirst vertical surface VS1 of the drain-select-level isolation structure80S and adjoins a top edge of a second vertical surface VS2 of thedrain-select-level isolation structure 80S.

As shown in FIG. 15D, each vertical metallic spacer 446′ can include asecond metallic barrier liner 446A′ having a same composition andthickness as a first metallic barrier liner 446A of thedrain-select-level electrodes 446. Further, each vertical metallicspacer 446′ can include a second metallic fill material portion 446B′having a same composition and lateral thickness as a portion of a firstmetallic fill material portion 446B within a vertical connection portion446V of a drain-select-level electrode 446. Each vertical metallicspacer 446′ contacts a sidewall of a dielectric divider structure 76 anda drain-select-level isolation structure 80S. Thus, each of the verticalmetallic spacers 446′ can comprise a respective second metallic barrierlayer 446A′ having a same composition and a same thickness as the firstmetallic barrier layers 446A, and can comprise a respective secondmetallic fill material portion 446B′ having a same composition as thefirst metallic fill material portions 446B.

Referring to FIGS. 16A and 16B, a second exemplary structure accordingto a second embodiment of the present disclosure is illustrated at theprocessing steps of FIGS. 3A and 3B of the first embodiment. The secondexemplary structure of FIGS. 16A and 16B can be the same as the firstexemplary structure of FIGS. 3A and 3B.

Referring to FIGS. 17A and 17B, the second exemplary structure isillustrated at the processing steps of FIGS. 5A and 5B. The processingsteps of FIGS. 4, 5A, and 5B can be modified to form drain-select-levelsacrificial line structures 73 only at locations of the first subset 51of the drain-select-level sacrificial line structures 73 of the firstexemplary structure without forming any drain-select-level sacrificialline structure 73 adjacent to area 79A at locations at which the secondsubset S2 of the drain-select-level sacrificial line structures 73. Inother words, the pattern of the drain-select-level sacrificial linestructures 73 in the second exemplary structure is modified from thepattern of the drain-select-level sacrificial line structures 73 suchthat only the pattern of the first subset 51 of the drain-select-levelsacrificial line structures 73 in the first exemplary structure ispresent in the second exemplary structure.

Referring to FIGS. 18A and 18B, multiple parallel rows of memoryopenings 49 are formed through the drain-select-level alternating stack(132, 142), the alternating stack (32 42), and the drain-select-levelsacrificial line structures 73. Memory openings 49 within each row arearranged along the first horizontal direction hd1, which is parallel tothe lengthwise direction of the drain-select-level sacrificial linestructures 73. The multiple parallel rows are laterally spaced apartalong the second horizontal direction hd2. A pair of rows (R1, R2) ofmemory openings 49 can pass through each drain-select-level sacrificialline structure 73. A respective row R1 or R2 of memory openings 49passes through each lengthwise sidewall of each drain-select-levelsacrificial line structure 73.

Segments of each of the drain-select-level sacrificial line structures73 are etched during formation of the multiple parallel rows of openings49. Each of the drain-select-level sacrificial line structures 73 can bepatterned to include a respective pair of laterally alternatingsequences of planar vertical sidewall segments 73P and concave verticalsidewall segments 73C during formation of the memory openings 49. Thememory openings can extend to a top surface of the semiconductormaterial layer 10. Additional openings can be formed in the contactregion 300 concurrently with formation of the memory openings 49. Suchadditional openings are herein referred to as support openings, whichcan be employed to form support pillar structures therein.

Referring to FIGS. 19A and 19B, the processing steps of FIGS. 7A and 7Bcan be performed on the second exemplary structure. Memory opening fillstructures 58 are formed within each memory opening 49. Each memoryopening fill structure 58 can include a memory film 50, a verticalsemiconductor channel 60, an optional dielectric core 62, a drain region63, and a dielectric memory opening cap portion 64. Each contiguouscombination of a memory film 50 and a vertical semiconductor channel 60constitutes a memory stack structure 55. The memory stack structures 55are formed in the multiple parallel rows of memory openings 49 throughthe alternating stack, the drain-select-level alternating stack (132,142), and the drain-select-level sacrificial line structures 73.

Referring to FIGS. 20A and 20B, a photoresist layer (not shown) can beapplied over the topmost drain-select-level insulating layer 132T, andcan be lithographically patterned to form openings in areas 79A. Thepattern in the photoresist layer can be transferred through thedrain-select-level alternating stack (132, 142) and the alternatingstack (32, 42) employing an anisotropic etch to form backside trenches79. Each backside trench 79 can vertically extend from the top surfaceof the topmost drain-select-level insulating layer 132T at least to thetop surface of the substrate (9, 10), and laterally extend through thememory array region 100 and the contact region 300.

In one embodiment, the backside trenches 79 can laterally extend alongthe first horizontal direction hd1 and can be laterally spaced apartamong one another along the second horizontal direction hd2 that isperpendicular to the first horizontal direction. The memory stackstructures 55 (included in the memory opening fill structures 58) can bearranged in rows that extend along the first horizontal direction hd1.Each backside trench 79 can have a uniform width that is invariant alongthe lengthwise direction (i.e., along the first horizontal directionhd1). Multiple rows of memory stack structures 55 can be located betweena neighboring pair of a backside trench 79 and a drain-select-levelsacrificial line structure 73, or between a neighboring pair ofdrain-select-level sacrificial line structures 73. In one embodiment,the backside trenches 79 can include a source contact opening in which asource contact via structure can be subsequently formed. The photoresistlayer can be removed, for example, by ashing.

Referring to FIGS. 21A and 21B, word-line-level backside recesses 43,source-select-level backside recesses, and first drain-select-levelbackside recesses 143 can be formed concurrently (i.e., simultaneouslywithin a same processing step) by isotropically etching theword-line-level sacrificial material layers 42 and first segments ofeach of the drain-select-level sacrificial material layers 142 that arephysically exposed the backside trenches 79 employing an isotropic etchprocess. An isotropic etchant that selectively etches the materials ofthe word-line-level sacrificial material layers 42 and thedrain-select-level sacrificial material layers 142 with respect to thematerials of the insulating layers 32 and the drain-select-levelinsulating layers 132 can be employed in the isotropic etch process. Theisotropic etchant can be introduced into the backside trenches 79,during the isotropic etch process while remaining portions of thedrain-select-level sacrificial line structures 73 protect secondsegments (i.e., additional segments) of each of the drain-select-levelsacrificial material layers 142. Specifically, the combination of thetopmost drain-select-level insulating layer 132T and thedrain-select-level sacrificial line structures 73 prevent the etchantfrom accessing the second segments of each of the drain-select-levelsacrificial material layers 142. Thus, the drain-select-levelsacrificial line structures 73 protect the second segments ofdrain-select-level sacrificial material layers 142 from the isotropicetchant.

Word-line-level backside recesses 43 are formed in volumes from whichthe word-line-level sacrificial material layers 42 are removed. Firstdrain-select-level backside recesses 143 are formed in volumes fromwhich the first segments of the drain-select-level sacrificial materiallayers 142 are removed. The removal of the materials of theword-line-level sacrificial material layers 42 and the first segments ofthe drain-select-level sacrificial material layers 142 can be selectiveto the first material of the insulating layers 32, the material of thedrain-select-level isolation layers 132, the material of theretro-stepped dielectric material portion 65, the semiconductor materialof the semiconductor material layer 10, and the material of theoutermost layer of the memory films 50. In one embodiment, theword-line-level sacrificial material layers 42 and thedrain-select-level sacrificial material layers 142 can include siliconnitride, and the materials of the insulating layers 32, thedrain-select-level isolation layers 132, and the retro-steppeddielectric material portion 65 can be selected from silicon oxide anddielectric metal oxides. The same etch process can be employed as in theprocessing steps of FIGS. 9A and 9B of the first embodiment.

Each word-line-level backside recess 43 can be a laterally extendingcavity having a lateral dimension that is greater than the verticalextent of the cavity. Each first drain-select-level backside recess 143can be a laterally extending cavity having a lateral dimension that isgreater than the vertical extent of the cavity. A plurality ofword-line-level backside recesses 43 can be formed in the volumes fromwhich the second material of the word-line-level sacrificial materiallayers 42 is removed. A plurality of first drain-select-level backsiderecesses 143 can be formed in the volumes from which the material of thedrain-select-level sacrificial material layers 142 is removed. Thememory openings in which the memory stack structures 55 are formed areherein referred to as front side openings or front side cavities incontrast with the word-line-level backside recesses 43. In oneembodiment, the memory array region 100 comprises an array of monolithicthree-dimensional NAND strings having a plurality of device levelsdisposed above the substrate (9, 10). In this case, each word-line-levelbackside recess 43 can define a space for receiving a respective wordline of the array of monolithic three-dimensional NAND strings.

Referring to FIGS. 22A and 22B, a backside blocking dielectric layer(not expressly illustrated) can be optionally formed at peripheralportions of the word-line-level backside recesses 43, the firstdrain-select-level backside recesses 143, and the backside trenches 79by a conformal deposition process. The backside blocking dielectriclayer, if present, comprises a dielectric material that functions as acontrol gate dielectric for the control gates to be subsequently formedin the word-line-level backside recesses 43. In case the blockingdielectric layer 52 is present within each memory opening, the backsideblocking dielectric layer is optional. In case the blocking dielectriclayer 52 is omitted, the backside blocking dielectric layer is present.For example, the backside blocking dielectric layer can include adielectric metal oxide such as aluminum oxide.

Word-line-level electrically conductive layers 46, source select gateelectrodes, and first segments of drain-select level electricallyconductive layers are formed in the word-line-level backside recesses43, the source-select-level recesses and in the first drain-select-levelbackside recesses 143 simultaneously. The first segments ofdrain-select-level electrically conductive layers are herein referred toas first drain-select-level electrically conductive layers 146.

For example, at least one conductive material can be conformallydeposited in the word-line-level backside recesses 43 and the firstdrain-select-level backside recesses 143. For example, a combination ofa metallic barrier layer and a metal fill material can be deposited inthe word-line-level backside recesses 43 and the firstdrain-select-level backside recesses 143. The metallic barrier layerincludes an electrically conductive metallic material that can functionas a diffusion barrier layer and/or adhesion promotion layer for ametallic fill material to be subsequently deposited. The metallicbarrier layer can include a conductive metallic nitride material such asTiN, TaN, WN, or a stack thereof. In one embodiment, the metallicbarrier layer can be deposited by a conformal deposition process such aschemical vapor deposition (CVD) or atomic layer deposition (ALD). Thethickness of the metallic barrier layer can be in a range from 2 nm to 8nm, such as from 3 nm to 6 nm, although lesser and greater thicknessescan also be employed. In one embodiment, the metallic barrier layer canconsist essentially of a conductive metal nitride such as TiN.

The metal fill material can be deposited on the metallic barrier layerto fill remaining volumes of the word-line-level backside recesses 43and the first drain-select-level backside recesses 143. The metallicfill material can be deposited by a conformal deposition method, whichcan be, for example, chemical vapor deposition (CVD), atomic layerdeposition (ALD), electroless plating, electroplating, or a combinationthereof. In one embodiment, the metallic fill material can consistessentially of at least one elemental metal. The at least one elementalmetal of the metallic fill material layer can be selected, for example,from tungsten, cobalt, ruthenium, titanium, and tantalum. In oneembodiment, the metallic fill material layer can consist essentially ofa single elemental metal.

Excess portions of the deposited metallic material in the backsidetrenches 79 and over the topmost drain-select-level insulating layer132T can be etched back, for example, by an isotropic wet etch, ananisotropic dry etch, or a combination thereof. Remaining portions ofthe deposited metallic material in the word-line-level backside recesses43 comprise word-line-level electrically conductive layers 46. Remainingportions of the deposited metallic material in the firstdrain-select-level backside recesses 143 comprise firstdrain-select-level electrically conductive layers 146H. Eachword-line-level electrically conductive layer 46 can be a conductiveline structure. Thus, the word-line-level sacrificial material layers 42can be replaced with the word-line-level electrically conductive layers46. Each word-line-level electrically conductive layer 46 can include aportion of the metallic barrier layer and a portion of the metallic fillmaterial. Each first drain-select-level electrically conductive layer146H can be a conductive line structure. Thus, the first segments of thedrain-select-level sacrificial material layers 142 can be replaced withthe first drain-select-level electrically conductive layers 146H. Eachfirst drain-select-level electrically conductive layer 146H can includea portion of the metallic barrier layer and a portion of the metallicfill material.

Referring to FIGS. 23A and 23B, the processing steps of FIGS. 11A and11B can be performed to form a dielectric divider structure 76 withineach backside trench 79. In one embodiment, each dielectric dividerstructure 76 can be a dielectric wall structure laterally extendingalong the first horizontal direction hd1 and vertically extendingthrough an alternating stack of the insulating layers 32 and theword-line-level electrically conductive layers 46 and through thealternating stack of the drain-select-level insulating layers 132 andthe first drain-select-level electrically conductive layers 146H. In oneembodiment, the dielectric divider structure 76 can be formed in atubular shape, for example, by deposition of a conformal dielectricmaterial liner and an anisotropic etch process, and a conductive contactvia structure may be formed within a cavity in the tubular dielectricdivider structure 76. In this case, a source region (not shown) may beformed in an upper portion of the semiconductor material layer 10underlying the backside trench 79.

In one embodiment, each dielectric divider structure 76 includes a pairof lengthwise sidewalls that laterally extend along the first horizontaldirection hd1 and vertically extends through the alternating stack ofthe insulating layers 32 and the word-line-level electrically conductivelayers 46 and through the levels of the first drain-select-levelelectrically conductive layers 146H that correspond to the levels of thedrain-select level sacrificial material layers 142.

Referring to FIGS. 24A and 24B, remaining portions of thedrain-select-level sacrificial line structures 73 can be subsequentlyremoved by a selective etch process that etches the material of thedrain-select-level sacrificial line structures 73 selective to thematerials of the dielectric memory opening cap portions 64, the topmostdrain-select-level insulating layer 132T, and the dielectric dividerstructures 76. For example, if the drain-select-level sacrificial linestructures 73 include amorphous silicon or polysilicon, a wet etchprocess employing hot trimethyl-2 hydroxyethyl ammonium hydroxide (“hotTMY”), tetramethyl ammonium hydroxide (TMAH), or ammonium hydroxide canbe employed to remove the drain-select-level sacrificial line structures73. Drain-select-level isolation trenches 71 can be formed in thevolumes from which the drain-select-level sacrificial line structures 73are removed.

Referring to FIGS. 25A and 25B, the second segments (i.e., the remainingsegments) of the drain-select-level sacrificial material layers 142 areremoved by a selective etch process that etches the material of thesecond segments of the drain-select-level sacrificial material layers142 without etching the materials of the drain-select-level insulatinglayers 132, the first drain-select-level electrically conductive layers146H, or the dielectric divider structures 76. For example, if thedrain-select-level sacrificial material layers 142 include siliconnitride and if the drain-select-level insulating layers 132 or thedielectric divider structures 76 include silicon oxide materials, thesecond segments of the drain-select-level sacrificial material layers142 can be removed by a wet etch process employing hot phosphoric acidprovided into the drain-select-level isolation trenches 71. Seconddrain-select-level backside recesses 243 are formed in volumes fromwhich the second segments of the drain-select-level sacrificial materiallayers 142 are removed through the drain-select-level isolation trenches71.

Referring to FIGS. 26A and 26B, at least one metallic fill material isdeposited in the second drain-select-level backside recesses 243 throughthe drain-select-level isolation trenches 71, and peripheral portions ofthe drain-select-level isolation trenches 71 by at least one conformaldeposition process. The at least one metallic fill material can include,for example, a metallic barrier liner including a conducive metalnitride material (such as TiN, TaN, or WN) and a metal fill materialsuch as tungsten, cobalt, molybdenum, and/or ruthenium. Thethickness(es) of the at least one metallic material can be selected suchthat the drain-select-level isolation trenches 71 are not completelyfilled with the at least one metallic fill material.

An anisotropic etch process is performed to remove horizontal portionsof the at least one metallic fill material from above the topmostdrain-select-level insulating layer 132T and from the bottom portion ofeach drain-select-level isolation trench 71. Each remaining portion ofthe at least one metallic fill material filling the seconddrain-select-level backside recesses 243 constitute a strip of adrain-select-level electrically conductive layer, which is hereinreferred to as a second drain-select-level isolation conductive layer246H. Each remaining vertical portion of the at least one metallic fillmaterial adjoined to a respective set of first drain-select-levelelectrically conductive layers 146H constitutes a first verticalconnection portion 146V. Each contiguous set of a first verticalconnection portion 146V and first drain-select-level electricallyconductive layers 146H constitute a first drain-select-level electrode146. Each remaining vertical portion of the at least one metallic fillmaterial adjoined to a respective set of second drain-select-levelelectrically conductive layers 246H constitutes a second verticalconnection portion 246V. Each contiguous set of at least one secondvertical connection portion 246V and second drain-select-levelelectrically conductive layers 246H constitute a seconddrain-select-level electrode 246. In one embodiment, a seconddrain-select-level electrode 246 can include two second verticalconnection portions 246V adjoined to two or more seconddrain-select-level electrically conductive layers 246H.

A drain-select-level cavity 71′ that generally extends along the firsthorizontal direction hd1 can be located within each drain-select-levelisolation trench 71. Each first drain-select-level electricallyconductive layer 146 can contact a sidewall of a respective one of thedielectric divider structures 76 that laterally extend along the firsthorizontal direction hd1. Each second drain-select-level electricallyconductive layer 246H can be formed in volumes from which a secondsegment of a drain-select-level sacrificial material layer 142 isremoved.

Referring to FIGS. 27A-27E, a dielectric cap layer 80 is formed bydepositing a dielectric material such as a silicon oxide material overthe topmost drain-select-level insulating layer 132T and in thedrain-select-level cavities 71′. Each portion of the dielectric caplayer 80 that fills a respective drain-select-level cavity 71′ is hereinreferred to as a drain-select-level isolation structure 80S. Thus, thedrain-select-level isolation structures 80S are formed within volumesfrom which the remaining portions of the drain-select-level sacrificialline structures 73 are removed.

Each first drain-select-level electrode 146 can include multiple firstmetallic barrier liners 146A located between a neighboring pair ofdrain-select-level insulating layers 132 or between a bottommostdrain-select-level insulating layer 132 and a topmost insulating layer32. Each first drain-select-level electrode 146 can include multiplefirst metallic fill material portions 146B that consists essentially ofan elemental metal or an intermetallic alloy. Each first metallic fillmaterial portion 146B can be embedded within a respective one of thefirst metallic barrier liners 146A. Each first metallic barrier liner146A and each first metallic fill material portion 146B can contact asidewall of a respective one of the dielectric divider structures 76.

Each first drain-select-level electrode 146 includes a first metallicbarrier liner 146A that continuously extends from a bottommost surfaceof the first drain-select-level electrode 146 to a topmost surface ofthe first drain-select-level electrode 146. For example, the firstmetallic barrier liner 146A of each first drain-select-level electrode146 can continuously extend from a bottom surface of a first verticalconnection portion 146V that contacts a recessed horizontal surface ofthe topmost insulating layer 32T to a top surface of the first verticalconnection portion 146V that contacts a stepped surface of adrain-select-level isolation structure 80S.

Each first drain-select-level electrode 146 can include a first metallicfill material portion 146B that consists essentially of an elementalmetal or an intermetallic alloy. The first metallic fill materialportion 146B can contact a non-vertical surface NVS (such as a steppedsurface) of a drain-select-level isolation structure 80S, for example,at the topmost surface located at a top end of the first verticalconnection portion 146V. The non-vertical surface NVS adjoins a bottomedge of a first vertical surface VS1 of the drain-select-level isolationstructure 80S and adjoins a top edge of a second vertical surface VS2 ofthe drain-select-level isolation structure 80S.

Each second drain-select-level electrode 246 includes a second metallicbarrier liner 246A that continuously extends from a bottommost surfaceof the second drain-select-level electrode 246 to a topmost surface ofthe second drain-select-level electrode 246. For example, the secondmetallic barrier liner 246A of each second drain-select-level electrode246 can continuously extend from a bottom surface of a second verticalconnection portion 246V that contacts a recessed horizontal surface ofthe topmost insulating layer 32T to a top surface of the second verticalconnection portion 246V that contacts a stepped surface of adrain-select-level isolation structure 80S.

Each second drain-select-level electrode 246 can include a secondmetallic fill material portion 246B that consists essentially of anelemental metal or an intermetallic alloy. The second metallic fillmaterial portion 246B can contact a non-vertical surface NVS (such as astepped surface) of a drain-select-level isolation structure 80S, forexample, at the topmost surface located at a top end of the secondvertical connection portion 246V. The non-vertical surface NVS adjoins abottom edge of a first vertical surface VS1 of the drain-select-levelisolation structure 80S and adjoins a top edge of a second verticalsurface VS2 of the drain-select-level isolation structure 80S.

The second metallic barrier layer 246A is deposited in a differentdeposition step than the first metallic barrier layer 146A. As such, thesecond metallic barrier layer 246A can differ from the first metallicbarrier layer 146A by thickness and/or by material composition. Forexample, the second metallic barrier layer 246A and the first metallicbarrier layer 146A can include titanium nitride in which the atomicratio of titanium atoms to nitrogen atoms are different, or one includestitanium nitride and the other includes tantalum or tungsten nitride.

Referring to all drawings of the first embodiment and the secondembodiment, each of the first and second exemplary structures caninclude a three-dimensional memory device. The three-dimensional memorydevice can include: an alternating stack of insulating layers 32 (i.e.,word-line-level insulating layers) and word-line-level electricallyconductive layers 46 located over a substrate (9, 10); a plurality ofmulti-level drain select electrodes {446, (146, 246)}, each comprising arespective vertical connection portion {446V, (146V, 246V)} contactingand electrically connected to a respective set of drain-select-levelelectrically conductive layers {446H, (146H, 246H)} that are verticallyspaced apart among one another and located over the alternating stack(32, 46); memory stack structures 55 comprising a respective verticalsemiconductor channel 60 and a respective memory film 50, wherein eachmemory film 50 has a respective sidewall that extends through thealternating stack (32, 46) and each level of the multi-level drainselect electrodes {446, (146, 246)}; and a first drain-select-levelisolation structure 80S overlying the alternating stack (32, 46),laterally extending along a first horizontal direction hd1 and locatedbetween a neighboring pair of the multi-level drain select electrodes{446, (146, 246)}, and including a pair of sidewalls that include arespective set of concave vertical sidewall segments, wherein at leastone multi-level drain select electrode (446, 246) of the plurality ofmulti-level drain select electrodes {446, (146, 246)} contacts asidewall of the first drain-select-level isolation structure 80S.

In one embodiment, at least one multi-level drain select electrode (446,246) of the plurality of multi-level drain select electrodes {446, (146,246)} comprises a metallic barrier layer (446A, 146A, 246A) and ametallic fill material portion (446B, 146B, 246B).

In one embodiment, each of the memory stack structures 55 is completelysurrounded by a respective one of the plurality of multi-level drainselect electrodes {446, (146, 246)}. In one embodiment, each verticalconnection portion {446V, (146V, 246V)} of the multi-level drain selectelectrodes {446, (146, 246)} comprises a sidewall including concavevertical sidewall segments located between a pair of the memory stackstructures 55. Each sidewall may include a laterally alternatingsequence of concave vertical metallic sidewall segments and planarvertical metallic sidewall segments, or a set of concave verticalmetallic sidewalls segments that are adjoined among one another.

In one embodiment, a dielectric divider structure 76 including a pair ofstraight sidewalls that laterally extend along the first horizontaldirection hd1 and vertically extending through the alternating stack(32, 46) can be provided. In one embodiment, the dielectric divider 76structure is laterally spaced from the drain-select-level isolationstructures 80S.

In one embodiment, a vertical metallic spacer 446′ can contact asidewall of the dielectric divider structure 76 and a seconddrain-select-level isolation structure 80S laterally spaced from thefirst drain-select-level isolation structure 80S.

In one embodiment, the vertical metallic spacer 446′ comprises anadditional metallic barrier layer 446A′ having a same composition and asame thickness as the metallic barrier layer 446A of the multi-leveldrain select electrode 446 and comprises an additional metallic fillmaterial portion 446B′ having a same composition as the metallic fillmaterial portion 446B of the multi-level drain select electrode 446.

In one embodiment, the second drain-select-level isolation structure 80Soverlies the alternating stack (32, 42), laterally extends along a firsthorizontal direction hd1, and includes a sidewall including a set ofconcave vertical sidewall segments on one side and a vertical sidewallthat laterally extends along the first horizontal direction hd1 andcontacts the vertical metallic spacer 446′ on another side. In oneembodiment, the dielectric divider structure 76 contacts sidewalls of apair of multi-level drain select electrodes {446, (146, 246)} of theplurality of the multi-level drain select electrodes {446, (146, 246)}.

In the second embodiment, the second multi-level drain select electrode246 of the plurality of multi-level drain select electrodes (146, 246)contacts a sidewall of the first drain-select-level isolation structure80S. In this embodiment, the first multi-level drain select electrode146 is referred as an “additional” multi-level drain select electrode146 to indicate that it is present in addition to the second multi-leveldrain select electrode 246. Each drain-select-level electricallyconductive layer 146H within the additional multi-level drain selectelectrode 146 of the plurality of multi-level drain select electrodes(146, 246) comprises a first metallic barrier layer 146A and a firstmetallic fill material portion 146B that contact the dielectric dividerstructure 76 and does not contact the first drain-select-level isolationstructure 80S. In the second embodiment, a vertical connection portion146V of the additional multi-level drain select electrode 146 comprisesa second metallic barrier layer 246A contacting sidewalls of eachdrain-select-level electrically conductive layer 146H within theadditional multi-level drain select electrode 146; and a second metallicfill material portion 246B which is laterally spaced from the firstmetallic fill material portions 146B of the drain-select-levelelectrically conductive layers 146H of the additional multi-level drainselect electrode 146 by the first metallic barrier layers 146A and thesecond metallic barrier layer 246A, as shown in FIG. 27D.

In one embodiment, the three-dimensional memory device can comprise atleast one feature selected from: a first feature that the secondmetallic barrier layer 246A differs from the first metallic barrierlayers 146A of the drain-select-level electrically conductive layers146H of the additional multi-level drain select electrode 146 bythickness or by material composition; and/or a second feature that thesecond metallic fill material portion 246B differs from the firstmetallic fill material portions 146B of the drain-select-levelelectrically conductive layers 146H of the additional multi-level drainselect electrode 146 by material composition.

Referring to FIGS. 28A and 28B, a third exemplary structure can bederived from the first exemplary structure of FIG. 2 by omitting theprocessing steps of FIGS. 3A and 3B, performing the processing steps ofFIG. 4, omitting the processing steps of FIGS. 5A and 5B, and performingthe processing steps of FIGS. 6A, 6B, 7A, and 7B. Thus, an alternatingstack of insulating layers 32 and word-line-level spacer material layers42 is formed over a substrate (9, 10) without forming thedrain-select-level layers (132, 142) of the first and second embodimentsat this step. The word-line-level spacer material layers can be formedas, or can be subsequently replaced with, word-line-level electricallyconductive layers 46.

Word-line-level memory openings extending through the alternating stack(32, 42) are formed at the processing steps of the third embodiment thatcorrespond to the processing steps of FIGS. 6A and 6B of the firstembodiment. Word-line-level memory opening fill structures (50, 601, 62,602) (which are also referred to as lower memory opening fillstructures) are formed in the word-line-level memory openings at theprocessing steps of the third embodiment that correspond to theprocessing steps of FIGS. 7A and 7B of the first embodiment. Theword-line-level memory opening fill structures (50, 601, 62, 602) can beformed in rows that laterally extend along the first horizontaldirection hd1. Adjacent rows of word-line-level memory opening fillstructures (50, 601, 62, 602) are laterally spaced apart along thesecond horizontal direction hd2.

Specifically, a memory film 50 can be formed within each word-line-levelmemory opening. Each component of the memory film 50 of the thirdembodiment can have the same composition and thickness as thecorresponding component of the memory film 50 of the first and secondembodiments. A word-line-level semiconductor channel portion 601 isformed in the third embodiment in lieu of a vertical semiconductorchannel 60 of the first and second embodiments. The word-line-levelsemiconductor channel portion 601 can have the same composition andthickness as the vertical semiconductor channel 60 of the first andsecond embodiments. The dielectric core 62 of the third embodiment canbe the same as the dielectric core 62 of the first and secondembodiments. A connection channel portion 602 having a doping of thefirst conductivity type can be formed in lieu of a drain region 63 ofthe first and second embodiments at the processing step that correspondto the processing steps of FIGS. 7A and 7B that form the drain regions63. In this case, the connection channel portion 602 can have the sametype of doping as the word-line-level semiconductor channel portion 60.The atomic concentration of dopants of the first conductivity type inthe word-line-level semiconductor channel portion 601 may be in a rangefrom 1.0×10¹⁴/cm³ to 1.0×10¹⁸/cm³, although lesser and greater atomicconcentrations can also be employed. The atomic concentration of dopantsof the first conductivity type in the connection channel portion 602 maybe in a range from 1.0×10¹⁸/cm³ to 2.0×10²¹/cm³, although lesser andgreater atomic concentrations can also be employed. The top surface ofthe topmost insulating layer 32T can be employed as a planarizationsurface during planarization processes. Formation of the dielectricmemory opening cap portions 64 can be omitted. Thus, the top surfaces ofthe connection channel portions 602 can be coplanar with the top surfaceof the topmost insulating layer 32T.

In one embodiment, the word-line-level spacer material layers are formedas word-line-level sacrificial material layers 42 and are subsequentlyreplaced with the word-line-level electrically conductive layers 46 byforming backside trenches 79 and word-line-level backside recesses 43,and by depositing at least one conductive material in theword-line-level backside recesses 43 as in the first and secondembodiments. In this case, the word-line-level backside recesses 43 canbe formed by isotropically etching the word-line-level sacrificialmaterial layers 42 employing an isotropic etchant provided into thebackside trench 79. The word-line-level electrically conductive layers46 are formed in the word-line-level backside recesses 43.

A dielectric divider structure 176 can be formed within each backsidetrench 79 by filling the backside trenches 79 with a dielectricmaterial. The dielectric divider structure 176 can include a pair oflengthwise sidewalls that laterally extend along a first horizontaldirection hd1 and can vertically extends-through an alternating stack ofthe insulating layers (i.e., the word-line-level insulating layers) 32and the word-line-level electrically conductive layers 46. In this case,a top surface of the dielectric divider structure can be coplanar withthe top surface of the topmost insulating layer 32T.

Referring to FIGS. 29A and 29B, an insulating cap layer 70 and adielectric etch stop material layer 170 may be optionally formed abovethe alternating stack (32, 46) and the word-line-level memory openingfill structures (50, 601, 62, 602). The insulating cap layer 70 caninclude a dielectric material such as undoped silicate glass or a dopedsilicate glass. The dielectric etch stop material layer 170 includes amaterial, such as aluminum oxide, that is different from the material ofthe insulating cap layer 70. The dielectric etch stop material layer 170can function as an etch stop layer during a subsequent anisotropic etchprocess that forms drain-select-level memory openings. The thickness ofthe insulating cap layer 70 can be in a range from 20 nm to 200 nm,although lesser and greater thicknesses can also be employed. Thethickness of the dielectric etch stop material layer 170 can be in arange from 10 nm to 100 nm, although lesser and greater thicknesses canalso be employed.

Referring to FIGS. 30A and 30B, an alternating stack ofdrain-select-level insulating layers 132 and drain-select-levelsacrificial material layers 242 can be formed over the dielectric etchstop material layer 170, which overlies the dielectric dividerstructures. The drain-select-level sacrificial material layers 242 arespaced apart by the drain-select-level insulating layers 132. Thedrain-select-level insulating layers 132 includes a dielectric materialsuch as undoped silicate glass or a doped silicate glass. Thedrain-select-level sacrificial material layers 242 include a sacrificialmaterial that can be removed selective to the drain-select-levelinsulating layers 132. For example, the drain-select-level sacrificialmaterial layers 242 can include a semiconductor material such asamorphous silicon, polysilicon, or a silicon-germanium alloy. Thedrain-select-level insulating layers 132 and the drain-select-levelsacrificial material layers 242 can be deposited by an alternatingsequence of chemical vapor deposition processes that sequentiallydeposits each layer within the alternating stack of thedrain-select-level insulating layers 132 and the drain-select-levelsacrificial material layers 242. The thickness of each layer within thealternating stack of the drain-select-level insulating layers 132 andthe drain-select-level sacrificial material layers 242 may be in a rangefrom 20 nm to 50 nm, although lesser and greater thicknesses can also beemployed. The topmost drain-select-level insulating layer 132T may havea thickness in a range from 40 nm to 200 nm, although lesser and greaterthicknesses can also be employed.

Referring to FIGS. 31A and 31B, drain-select-level line trenches 172 canbe formed through the alternating stack of the drain-select-levelinsulating layers 132 and the drain-select-level sacrificial materiallayers 242. For example, an etch mask such as a patterned photoresistlayer can be formed over the topmost drain-select-level insulating layer132T. The dielectric etch stop material layer 170 can be employed as anetch stop layer during an anisotropic etch process employed to form thedrain-select-level line trenches 172. The etch mask layer can besubsequently removed, for example, by ashing. The drain-select-levelline trenches 172 can laterally extend along a first horizontaldirection hd1. In one embodiment, the drain-select-level line trenches172 can be formed such that each drain-select-level line trench 172partially overlaps in area with a neighboring pair of rows ofword-line-level memory opening fill structures (50, 601, 62, 602) thatlaterally extend along the first horizontal direction hd1 in a planview, i.e., in a see-through view along a direction perpendicular to thetop surface of the substrate (9, 10).

Referring to FIGS. 32A and 32B, a sacrificial material is deposited inthe drain-select-level line trenches 172 to form drain-select-levelsacrificial line structures 173. The sacrificial material of thedrain-select-level sacrificial line structures 173 can be the same as,or can be different from, the sacrificial material of thedrain-select-level sacrificial material layers 242. In one embodiment,the drain-select-level sacrificial line structures 173 can include thesame material as the sacrificial material of the drain-select-levelsacrificial material layers 242. In another embodiment, thedrain-select-level sacrificial line structures 173 can include asacrificial material that is different from the sacrificial material ofthe drain-select-level sacrificial material layers 242. In anillustrative example, the drain-select-level sacrificial line structures173 can include silicon nitride, and the sacrificial material of thedrain-select-level sacrificial material layers 242 can include asemiconductor material such as amorphous silicon, polysilicon, or asilicon-germanium alloy. Each drain-select-level sacrificial linestructure 173 vertically extends through each of the drain-select-levelsacrificial material layers 242 and the drain-select-level insulatinglayers 132.

Referring to FIGS. 33A and 33B, a photoresist layer (not shown) can beapplied over the topmost drain-select-level insulating layer 132T, andcan be lithographically patterned to form opening having the samepattern as the word-line-level memory opening fill structures (50, 601,62, 602), i.e., the pattern of the word-line-level memory openings. Inone embodiment, the same lithographic mask previously employed tolithographically expose a photoresist layer that functions as an etchmask for patterning the word-line-level memory openings can be employedagain at this processing step to pattern the photoresist layer. Thepattern of the openings in the photoresist layer can be transferredthrough the drain-select-level alternating stack (132, 242) and thedrain-select-level sacrificial line structure 173 to form openingtherethrough, which are herein referred to as drain-select-level memoryopenings 149. Each drain-select-level memory opening 149 (which are alsoreferred to as upper memory openings herein) overlies, and has an arealoverlap with in a plan view, with an underlying one of theword-line-level memory opening fill structures (50, 601, 62, 602).

The drain-select-level memory openings 149 can be formed throughperipheral portions of the drain-select-level sacrificial linestructures 173. Multiple parallel rows of drain-select-level memoryopenings 149 can be arranged along the first horizontal direction hd1through the drain-select-level spacer material layers 242 and thedrain-select-level sacrificial line structures 173. The first horizontaldirection hd1 is parallel to a lengthwise direction of thedrain-select-level sacrificial line structures 173. Segments of each ofthe drain-select-level sacrificial line structures 173 are etched duringformation of the multiple parallel rows of drain-select-level memoryopenings 149. In one embodiment, each of the drain-select-levelsacrificial line structures 173 can be patterned to include a respectivepair of laterally alternating sequences of planar vertical sidewallsegments 173P and concave vertical sidewall segments 173C duringformation of the drain-select-level memory openings 149.

Referring to FIGS. 34A and 34B, a gate dielectric layer can besubsequently formed by conformal deposition of a gate dielectricmaterial such as silicon oxide and/or a dielectric metal oxide. The gatedielectric layer is herein referred to as a drain-select-level gatedielectric layer 150L. The thickness of the drain-select-level gatedielectric layer 150L can be in a range from 1 nm to 10 nm, althoughlesser and greater thicknesses can also be employed. A cover materiallayer 613L can be deposited over the drain-select-level gate dielectriclayer 150L by a conformal deposition process. The cover material layer613L can include a sacrificial material such as amorphous carbon or anon-sacrificial material such as a doped semiconductor material, such aspolysilicon or amorphous silicon, which has a doping of the firstconductivity type and is subsequently incorporated into adrain-select-level semiconductor channel portion. The thickness of thecover material layer 613L can be in a range from 1 nm to 20 nm, althoughlesser and greater thicknesses can also be employed.

Referring to FIGS. 35A and 35B, the drain-select-level memory openings149 are vertically extended through the etch stop dielectric layer 170and the insulating cap layer 70 by an anisotropic etch process. Theanisotropic etch process removes horizontal portions of the covermaterial layer 613L and the drain-select-level gate dielectric layer150L. Each remaining portion of the cover material layer 613L forms acover material spacer 613, which can have a tubular shape. A top surfaceof a connection channel portion 602 is physically exposed at the bottomof each drain-select-level memory openings 149 as vertically extended bythe anisotropic etch process. A patterned portion of thedrain-select-level gate dielectric layer 150L is present at an upperperiphery of each drain-select-level memory opening 149, which is hereinreferred to as a drain-select-level gate dielectric 150. The covermaterial spacer 613 within each drain-select-level memory opening 149may be subsequently removed in case the cover material spacer 613includes a sacrificial material, or may remain on an inner sidewall of adrain-select-level gate dielectric 150 in case the cover material spacer613 includes a semiconductor material such as poly silicon or amorphoussilicon.

Referring to FIGS. 36A and 36B, a doped semiconductor material having adoping of the first conductivity type can be deposited at a periphery ofthe unfilled volume of each drain-select-level memory opening 149. Theatomic concentration of dopants of the first conductivity type in thedoped semiconductor material may be in a range from 1.0×10¹⁴/cm³ to1.0×10¹⁸/cm³, although lesser and greater atomic concentrations can alsobe employed. In case the drain-select-level memory openings 149 are notcompletely filled with the doped semiconductor material, a dielectricmaterial such as silicon oxide may be deposited to fill unfilled volumesof the drain-select-level memory openings 149. The dielectric materialcan be vertically recessed below the horizontal plane including the topsurface of the topmost drain-select-level insulating layer 132T by arecess etch process. Each remaining portion of the dielectric materialforms a drain-select-level dielectric core 162.

A doped semiconductor material having a doping of the secondconductivity type is formed in the recesses overlying thedrain-select-level dielectric cores 162. The doped semiconductormaterial having a doping of the second conductivity type may be formedby deposition of a semiconductor material having a doping of a secondconductivity type, or may be formed by deposition of an undopedsemiconductor material and by ion implantation of dopants of the secondconductivity type. Excess portions of the doped semiconductor materialhaving a doping of the first conductivity type and the dopedsemiconductor material having a doping of the second conductivity typecan be removed from above the horizontal plane including the top surfaceof the topmost drain-select-level insulating layer 132T by aplanarization process, which can employ a recess etch and/or chemicalmechanical planarization process. Each remaining portion of the dopedsemiconductor material having a doping of the first conductivity typeconstitutes a drain-select-level semiconductor channel portion 603. Eachremaining portion of the doped semiconductor material having a doping ofthe second conductivity type constitutes a drain region 63. Atomicconcentration of dopants of the second conductivity type in the drainregions 63 can be in a range from 5.0×10¹⁹/cm³ to 2.0×10²¹/cm³, althoughlesser and greater atomic concentrations can also be employed.

The set of all components that fill a drain-select-level memory opening149 is herein referred to as a drain-select-level structure (150, 603,162, 63). Each drain-select-level structure (150, 603, 162, 63) includesa gate dielectric, i.e., a drain-select-level gate dielectric 150, and adrain-select-level semiconductor channel portion 603. Eachdrain-select-level structure (150, 603, 162, 63) is formed on each ofthe memory stack structures 55 through portions of thedrain-select-level sacrificial material layers 242. A subset of thedrain-select-level structures (150, 603, 162, 63) is formed directly onthe drain-select-level sacrificial line structures 173. Thedrain-select-level structures (150, 603, 162, 63) can contact convexsidewalls of the drain-select-level sacrificial line structures 173 uponformation of the drain-select-level structures (150, 603, 162, 63).

Each contiguous set of a word-line-level semiconductor channel portion601, a connection channel portion 602, and a drain-select-levelsemiconductor channel portion 603 constitutes a vertical semiconductorchannel 60. Each contiguous set of a vertical semiconductor channel 60and a memory film 50 constitutes a memory stack structure 55 including avertical stack of memory elements configured to store electrical chargestherein. The memory stack structures 55 can be formed in the multipleparallel rows of openings, each of which includes a stack of aword-line-level opening and a drain-select-level memory opening. Thememory stack structures 55 extend through the alternating stack (32, 46)of the insulating layers 32 and the word-line-level electricallyconductive layers 46, the drain-select-level sacrificial material layers242, and the drain-select-level sacrificial line structures 173. Each ofthe drain-select-level sacrificial line structures 173 can be patternedto include a respective pair of laterally alternating sequences ofplanar vertical sidewall segments and concave vertical sidewall segmentsduring formation of the memory stack structures 55.

Referring to FIGS. 37A and 37B, a first dielectric cap layer 270 can beformed over the drain-select-level alternating stack (132, 242) and thedrain-select-level structures (150, 603, 162, 63). The first dielectriccap layer 270 can include a dielectric material such as silicon oxide,and can have a thickness in a range from 20 nm to 200 nm, althoughlesser and greater thicknesses can also be employed.

Referring to FIGS. 38A and 38B, a photoresist layer (not shown) can beapplied over the first dielectric cap layer 270, and can belithographically patterned to form openings in areas that overlie thedrain-select-level sacrificial line structures 173. In one embodiment,the photoresist layer may be patterned to form openings outside theareas of the drain regions 63 so that the drain regions 63 are notphysically exposed after formation of openings through the photoresistlayer. An etch process such as an anisotropic etch process can beperformed to transfer the pattern of the openings in the photoresistlayer through the first dielectric cap layer 270. Openings are formedthrough the first dielectric cap layer 270, and the top surface of eachdrain-select-level sacrificial line structure 173 can be physicallyexposed within the openings through the first dielectric cap layer 270.

Referring to FIGS. 39A and 39B, the drain-select-level sacrificial linestructure 173 can be removed selective to the drain-select-levelinsulating layers 132 by an isotropic etch process. For example, if thedrain-select-level sacrificial line structure 173 includes siliconnitride and if the drain-select-level insulating layers 132 includesilicon oxide, a wet etch process employing hot phosphoric acid may beperformed to remove the drain-select-level sacrificial line structure173 without removing the drain-select-level insulating layers 132.Drain-select-level isolation trenches 71 can be formed in volumes fromwhich the drain-select-level sacrificial line structure 173 are removed.

A photoresist layer (not shown) can be applied over the third exemplarystructure after, or prior to, removal of the drain-select-levelsacrificial line structures 173. Rectangular openings having an arealoverlap with a respective one of the dielectric divider structures 176can be formed in the photoresist layer by lithographic exposure anddevelopment. The pattern in the photoresist layer can be transferredthrough the alternating stack of the drain-select-level insulatinglayers 132 and drain-select-level sacrificial material layers 242employing an anisotropic etch process to form drain-select-level dividertrenches 279. The etch stop dielectric layer 170 can be employed as anetch stop structure during the anisotropic etch process. Eachdrain-select-level divider trench 279 can have a pair of lengthwisesidewalls that laterally extend along the first horizontal directionhd1. In one embodiment, at least 50%, which can be at least 80%, of thearea of each drain-select-level divider trench 279 can have an arealoverlap with an underlying dielectric divider structure 176. Thephotoresist layer can be subsequently removed, for example, by ashing.

Referring to FIGS. 40A and 40B, the drain-select-level sacrificialmaterial layers 242 are removed by a selective etch process that etchesthe material of the drain-select-level sacrificial material layers 242without etching the materials of the drain-select-level insulatinglayers 132, the first dielectric cap layer 270, or the dielectric etchstop material layer 170. For example, if the drain-select-levelsacrificial material layers 242 include amorphous silicon and if thedrain-select-level insulating layers 132 and the first dielectric caplayer 270 include silicon oxide materials, the drain-select-levelsacrificial material layers 242 can be removed by a wet etch processemploying hot trimethyl-2 hydroxyethyl ammonium hydroxide (“hot TMY”),tetramethyl ammonium hydroxide (TMAH), or ammonium hydroxide providedinto the drain-select-level isolation trenches 71 and thedrain-select-level divider trenches 279. Drain-select-level backsiderecesses 143 are formed in volumes from which the drain-select-levelsacrificial material layers 242 are removed through thedrain-select-level isolation trenches 71 and the drain-select-leveldivider trenches 279. The drain-select-level backside recesses 143 canbe adjoined to a neighboring pair of trenches of the plurality of thedrain-select-level isolation trenches 71 and the drain-select-leveldivider trenches 279.

Referring to FIGS. 41A and 41B, at least one metallic fill material canbe simultaneously deposited in the drain-select-level backside recesses143 through the drain-select-level isolation trenches 71 and thedrain-select-level divider trenches 279, and peripheral portions of thedrain-select-level isolation trenches 71 and the drain-select-leveldivider trenches 279 by at least one conformal deposition process. Theat least one metallic fill material can include, for example, a metallicbarrier liner including a conducive metal nitride material (such as TiN,TaN, or WN) and a metal fill material such as tungsten, cobalt,molybdenum, and/or ruthenium. The thickness(es) of the at least onemetallic material can be selected such that the drain-select-levelisolation trenches 71 and the drain-select-level divider trenches 279are not completely filled with the at least one metallic fill material.A continuous conductive material layer 346L can be formed within each ofthe drain-select-level backside recesses 143, at peripheral regions ofthe drain-select-level isolation trenches 71 and the drain-select-leveldivider trenches 279, and over the first dielectric cap layer 270. Adrain-select-level cavity 71′ can be formed within the unfilled volumeof each drain-select-level isolation trench 71.

Referring to FIGS. 42A and 42B, an anisotropic etch process is performedto remove horizontal portions of the continuous conductive materiallayer 346L from above the first dielectric cap layer 270 and from thebottom regions of the drain-select-level isolation trenches 71 and thedrain-select-level divider trenches 279. Each remaining portion of theat least one metallic fill material filling the drain-select-levelbackside recesses 143 constitute a drain-select-level electricallyconductive layer 346H. Each remaining vertical portion of the at leastone metallic fill material adjoined to a respective set ofdrain-select-level electrically conductive layers 346H constitutes avertical connection portion 346V.

Each drain-select-level electrode 346 can be a multi-level drain selectelectrode 346 including multiple drain-select-level electricallyconductive layer 346H located at multiple drain select levels. Eachmulti-level drain select electrode 346 can include a respective verticalconnection portion 346V contacting and electrically connected to arespective set of drain-select-level electrically conductive layers 346Hlocated within volumes of the drain-select-level backside recesses. Thevertical connection portion 346V can be located within adrain-select-level isolation trench 71. Each contiguous set of at leastone vertical connection portion 346V and drain-select-level electricallyconductive layers 346H constitute a multi-level drain-select-levelelectrode 346. In one embodiment, a multi-level drain-select-levelelectrode 346 can include two vertical connection portions 346V adjoinedto two or more drain-select-level electrically conductive layers 346H.

A drain-select-level cavity 71′ that generally extends along the firsthorizontal direction hd1 can be located within each drain-select-levelisolation trench 71. Each drain-select-level electrically conductivelayer 346H at a drain select level can be formed in multiple portionsthat are laterally spaced apart by the drain-select-level cavities 71′and unfilled portions of the drain-select-level divider trenches 279.Each drain-select-level electrically conductive layer 346H can be formedin volumes from which a respective drain-select-level sacrificialmaterial layer 242 is removed.

Referring to FIGS. 43A-43F, a second dielectric material can bedeposited over the first dielectric cap layer 270 and in thedrain-select-level cavities 71′ and unfilled portions of thedrain-select-level divider trenches 279 to form a second dielectric caplayer 280. Each portion of the second dielectric cap layer 280 thatfills a respective drain-select-level cavity 71′ is herein referred toas a drain-select-level isolation structure 280S. Thus, thedrain-select-level isolation structures 280S are formed within volumesfrom which the remaining portions of the drain-select-level sacrificialline structures 73 are removed. Each portion of the second dielectriccap layer 280 that fills a remaining volume of a respectivedrain-select-level divider trenches 279 is herein referred to as adrain-select-level divider structure 276. Thus, the drain-select-leveldivider structures 276 are formed within volumes at the levels of thedrain-select-level insulating layers 132 and the drain-select-levelelectrically conductive layers 346H over a respective one of thedielectric divider structures 176.

A drain-select-level isolation structure 280S is formed within eachremaining volume of the drain-select-level isolation trenches 71 afterformation of the multi-level drain select electrodes 346. Adrain-select-level divider structure 276 can laterally contact a pair ofmulti-level drain select electrodes 346 of the plurality of themulti-level drain select electrodes 346, and can be formed above arespective dielectric divider structure 176 within an area having atleast partial overlap with the area of the dielectric divider structure176.

In one embodiment, each drain-select-level electrode 346 can include ametallic barrier liner 346A that continuously extends from a bottommostsurface of the drain-select-level electrode 346 to a topmost surface ofthe drain-select-level electrode 346. For example, the metallic barrierliner 346A of each drain-select-level electrode 346 can continuouslyextend from a bottom surface of a vertical connection portion 346V thatcontacts a recessed horizontal surface of the topmost insulating layer32T to a top surface of the vertical connection portion 346V thatcontacts a stepped surface of a drain-select-level isolation structure280S.

Each drain-select-level electrode 346 can include a metallic fillmaterial portion 346B that consists essentially of an elemental metal oran intermetallic alloy. The metallic fill material portion 346B cancontact a non-vertical surface NVS (such as a horizontal steppedsurface) of a drain-select-level isolation structure 280S, for example,at the topmost surface located at a top end of the vertical connectionportion 346V. The non-vertical surface NVS adjoins a bottom edge of avertical surface VS1 of the drain-select-level isolation structure 280Sand adjoins a top edge of a vertical surface VS2 of thedrain-select-level isolation structure 280S.

Referring to all drawings of the third exemplary structure, the thirdexemplary structure can include a three-dimensional memory device. Thethree-dimensional memory device can include: an alternating stack ofinsulating layers 32 and word-line-level electrically conductive layers46 located over a substrate (9, 10); a plurality of multi-level drainselect electrodes 346 comprising a respective vertical connectionportion 346V contacting and electrically connected to a respective setof drain-select-level electrically conductive layers 346H that arevertically spaced apart among one another and located over thealternating stack (32, 46); memory stack structures 55 comprising arespective vertical semiconductor channel 60 laterally surrounded by arespective memory film 50 extending through the alternating stack (32,46), and laterally surrounded by a respective gate dielectric 150extending through a respective one of the multi-level drain selectelectrodes 346; and a drain-select-level isolation structure 280Soverlying the alternating stack (32, 46), laterally extending along afirst horizontal direction hd1 and located between a neighboring pair ofthe multi-level drain select electrodes 346, and including a pair ofsidewalls that include a respective set of concave vertical sidewallsegments, wherein each of the multi-level drain select electrodes 346contacts a sidewall of a subset of the gate dielectrics 150.

In one embodiment, the upper portion of each of the memory stackstructures 55 containing an upper portion of the semiconductor channel60 and the gate dielectric 150 is completely surrounded by a respectiveone of the plurality of multi-level drain select electrodes 346.

In one embodiment, each vertical semiconductor channel 60 comprises: aword-line-level semiconductor channel portion 601 vertically extendingthrough each of the word-line-level electrically conductive layers 46;and a drain-select-level semiconductor channel portion 603 verticallyextending through each level of the drain-select-level electricallyconductive layers 346H and electrically connected to an upper portion ofthe word-line-level semiconductor channel portion 601. In oneembodiment, each vertical semiconductor channel 60 comprises aconnection channel portion 602 contacting a top end of theword-line-level semiconductor channel portion 601 and a bottom end ofthe drain-select-level semiconductor channel portion 603 and laterallysurrounded by a respective one of the memory films 50.

In one embodiment, the three-dimensional memory device comprises: aninsulating cap layer 70 located over the alternating stack (32, 46) andunderlying the multi-level drain select electrodes 346; and an etch stopdielectric layer 170 comprising a material different from the insulatingcap layer, overlying the insulating cap layer 70 and underlying themulti-level drain select electrodes 346, wherein the drain-select-levelsemiconductor channel portion 603 vertically extends through theinsulating cap layer 70 and the etch stop dielectric layer 170.

In one embodiment, each multi-level drain select electrode 346 comprisesa metallic barrier layer 346A and a metallic fill material portion 346B.The metallic barrier layer 346A contacts a subset of the gatedielectrics 150. In one embodiment, each vertical connection portion346V of the multi-level drain select electrodes 346 comprises a sidewallincluding concave vertical sidewall segments. The concave verticalsidewall segments may be adjoined to each another, or may be adjoinedthrough planar vertical sidewall segments.

In one embodiment, each vertical connection portion 346V of themulti-level drain select electrodes 346 has a greater vertical extentthan a vertical distance between a horizontal plane including a topmostsurface of the drain-select-level electrically conductive layers 346Hand a horizontal plane including a bottommost surface of thedrain-select-level electrically conductive layers 346H.

In one embodiment, the vertical connection portions 346V of themulti-level drain select electrodes 346 contact first areas of sidewallsof a subset of the gate dielectrics 150 (as illustrated in FIG. 43D);and the drain-select-level electrically conductive layers 346H contactsecond areas of the sidewalls of the subset of the gate dielectrics 150(as illustrated in FIG. 43F).

In one embodiment, each of the vertical connection portions 346Vcomprises: a laterally alternating sequence of planar vertical innersidewall segments (that contact sidewalls of the drain-select-levelinsulating layers 132) and concave vertical inner sidewall segments thatcontact a respective gate dielectric 150; and a laterally alternatingsequence of planar vertical outer sidewall segments and convex verticalouter sidewall segments that contact a sidewall of the respective one ofthe drain-select-level isolation structures 280S.

In one embodiment, the three-dimensional memory device comprisesdrain-select-level insulating layers 132 located between each verticallyneighboring pair of the plurality of the drain-select-level electricallyconductive layers 346H.

In one embodiment, the metallic fill material portion 346B contacts anon-vertical surface NVS of the drain-select-level isolation structure280S, wherein the non-vertical surface NVS adjoins a bottom edge of afirst vertical surface VS1 of the drain-select-level isolation structure280S and adjoins a top edge of a second vertical surface VS2 of thedrain-select-level isolation structure 280S, as illustrated in FIG. 43E.

Referring to FIGS. 44A and 44B, each of the first, second, and thirdexemplary structures illustrated in FIGS. 15A-15D, 27A-27E, and 43A-43Fcan be suitably wired by forming various contact via structures andadditional interconnect-level dielectric material layers. For example,drain contact via structures 88 are formed on a top surface of arespective one of the drain regions 63. Staircase-region contact viastructures 86 are formed in the staircase-region contact via cavitiesand on a top surface of a respective one of the various electricallyconductive layers (46, 146, 246, 346, 446). The staircase-region contactvia structures 86 can include drain select level contact via structuresthat contact the multi-level drain select electrodes (146, 246, 346,446). Further, the staircase-region contact via structures 86 caninclude word line contact via structures that contact theword-line-level electrically conductive layers 46 that function as wordlines for the memory stack structures 55. Peripheral-region contact viastructures 8P can be formed in the peripheral device region 200. In oneembodiment, a source region 61 may be formed underneath each backsidetrench 79 prior to formation of the dielectric divider structures 76. Inthis case, a surface portion of the semiconductor material layer 10 canfunction as a horizontal semiconductor channel 59. The dielectricdivider structures 76 can be formed in a tubular configuration, and asource contact via structure 81 can be formed within each dielectricdivider structure 76. Support pillar structures 20 including a same setof structural components as a memory opening fill structure 58 can beformed in the contact region 300. The support pillar structures 20 areelectrically inactive components that provide structural support whileword-line-level backside recesses 43 are present.

Referring to FIG. 45, an alternative configuration of the first, second,and third exemplary structures is illustrated, which includes a stack ofa planar insulating spacer layer 768, a planar conductive material layer6 (which can comprise a metallic plate), and source-level materiallayers 110 in lieu of a semiconductor material layer 10. In this case,buried source strap connections are formed between the verticalsemiconductor channels 60 and a source contact layer 114 within thesource-level material layers 110. In one embodiment, the source-levelmaterial layers 110 can include, from bottom to top, a lowersource-level material layer 112, the source contact layer 114, an uppersource-level material layer 116, a source-level insulating layer 117,and an optional source-select-level conductive layer 118. In this case,the source contact layer 114 can function as a source region for thevertical semiconductor channels 60.

Each of the exemplary structures can include a three-dimensional memorydevice. In one embodiment, the three-dimensional memory device comprisesa monolithic three-dimensional NAND memory device. The electricallyconductive layers 46 can comprise, or can be electrically connected to,a respective word line of the monolithic three-dimensional NAND memorydevice. The substrate (9, 10) can comprise a silicon substrate. Thevertical NAND memory device can comprise an array of monolithicthree-dimensional NAND strings over the silicon substrate. At least onememory cell (as embodied as a portion of a charge storage layer 54 at alevel of a word-line-level electrically conductive layer 46) in a firstdevice level of the array of monolithic three-dimensional NAND stringscan be located over another memory cell (as embodied as another portionof the charge storage layer 54 at a level of another word-line-levelelectrically conductive layer 46) in a second device level of the arrayof monolithic three-dimensional NAND strings. The silicon substrate cancontain an integrated circuit comprising a driver circuit (as embodiedas a subset of the least one semiconductor device 700) for the memorydevice located thereon. The word-line-level electrically conductivelayers 46 can comprise a plurality of control gate electrodes having astrip shape extending substantially parallel to the top surface of thesubstrate (9, 10), e.g., between a pair of backside trenches 79. Theplurality of control gate electrodes comprises at least a first controlgate electrode located in a first device level and a second control gateelectrode located in a second device level. The array of monolithicthree-dimensional NAND strings can comprise: a plurality ofsemiconductor channels (59, 60), wherein at least one end portion ofeach of the plurality of semiconductor channels (59, 60) extendssubstantially perpendicular to a top surface of the substrate (9, 10)and comprising a respective one of the vertical semiconductor channels60; and a plurality of charge storage elements (as embodied as portionsof the memory films 50, i.e., portions of the charge storage layer 54).Each charge storage element can be located adjacent to a respective oneof the plurality of semiconductor channels (59, 60).

Referring to FIG. 46, a fourth exemplary structure according to a fourthembodiment of the present disclosure can be derived from the thirdexemplary structure illustrated in FIGS. 28A and 28B by forming avertical layer stack including an insulating cap layer 70 anddrain-select-level material layers (470, 446L, 132). Generally, analternating stack of inter-word-line insulating layers 32 andword-line-level sacrificial material layers 42 can be formed over asubstrate. Memory openings 49 can be formed through the alternatingstack (32, 42). Memory opening fill structures (50, 601, 602, 62) can beformed in the memory openings 49. Each of the memory opening fillstructures (50, 601, 602, 62) comprises a memory film 50, aword-line-level semiconductor channel portion 601, and a connectionchannel portion 602. The vertical layer stack (70, 470, 446L, 132)including an insulating cap layer 70 and the drain-select-level materiallayers (470, 446L, 132) can be formed over the alternating stack and thememory opening fill structures (50, 601, 602, 62).

According to an embodiment of the present disclosure, thedrain-select-level material layers (470, 446L, 132) comprise an optionaletch stop dielectric layer 470, a drain select electrode layer 446L, anda drain-select-level insulating layer 132. The etch stop dielectriclayer 470 includes a dielectric material that functions as an etch stopmaterial. For example, the etch stop dielectric layer 470 can includesilicon nitride or a dielectric metal oxide such as aluminum oxide. Thethickness of the etch stop dielectric layer 470 can be in a range from 3nm to 30 nm, although lesser and greater thicknesses may also beemployed.

The drain select electrode layer 446L includes an electricallyconductive material. In one embodiment, the drain select electrode layer446L can include a heavily doped semiconductor material such as heavilydoped polysilicon or a heavily doped silicon-germanium alloy.Alternatively, the drain select electrode layer 446L includes a metallicmaterial such as Ti, Ta, W, TiN, TaN, and/or WN. The thickness of thedrain select electrode layer 446L can be in a range from 30 nm to 600nm, although lesser and greater thicknesses can also be employed.

The drain-select-level insulating layer 132 includes an insulatingmaterial such as silicon oxide, and may have a thickness in a range from30 nm to 600 nm, although lesser and greater thicknesses may also beemployed.

Referring to FIG. 47, drain-select-level isolation structures 80S anddrain-select-level insulating spacers 376 can be formed through thedrain-select-level material layers (470, 446L, 132). The pattern of thedrain-select-level isolation structures 80S can be the same as thepattern of the drain-select-level isolation structures 80S in thepreviously described embodiments. The pattern of the drain-select-levelinsulating spacers 376 can be the same as the pattern of thedrain-select-level divider trench 279 that is described above.

The drain-select-level isolation structures 80S and drain-select-levelinsulating spacers 376 can be formed by applying a photoresist layerover the drain-select-level insulating layer 132, lithographicallypatterning the photoresist layer to form openings that laterally extendalong a first horizontal direction (which can be the same as the firsthorizontal direction illustrated in FIG. 39A), forming line trenchesthrough the drain-select-level material layers (470, 446L, 132),removing the photoresist layer, and filling the line trenches with adielectric fill material, such as silicon oxide.

Each patterned portion of the drain select electrode layer 446Lconstitutes a drain select electrode 446. Generally, the drain selectelectrodes 446, the drain-select-level isolation structures 80S, and thedrain-select-level insulating spacers 376 can be formed by patterningand/or replacing portions of the vertical layer stack (70, 470, 446L,132). The drain select electrodes 446 are laterally spaced apart fromeach other by the drain-select-level isolation structures 80S and/or thedrain-select-level insulating spacers 376.

Referring to FIG. 48, drain-select-level memory openings 149 can beformed through the drain-select-level insulating layer 132, the drainselect electrodes 446, and the etch stop dielectric layer 470 over arespective one of the memory opening fill structures (50, 601, 602, 62).The pattern of the drain-select-level memory openings 149 may be thesame as the pattern of the drain-select-level memory openings 149illustrated in FIGS. 33A and 33B. The etch stop dielectric layer 470functions as an etch stop layer during the anisotropic (e.g., RIE) etchof the overlying layers. After forming the drain-select-level memoryopenings 149 through the drain select electrodes 446 and stopping on theetch stop dielectric layer 470, the etch chemistry may be adjusted toetch the remainder of the drain-select-level memory openings 149 throughthe etch stop dielectric layer 470. Lateral portions of thedrain-select-level isolation structures 80S that may be exposed in theopenings in the photoresist pattern during the anisotropic etch may alsobe collaterally etched, and thus removed.

Referring to FIG. 49, a gate dielectric layer can be formed by conformaldeposition of a gate dielectric material. The gate dielectric layer canhave the same material composition and the same thickness as the gatedielectrics 150 described above. Optionally, a semiconductor channelmaterial layer, such as amorphous silicon or polysilicon, can bedeposited over the gate dielectric layer.

An anisotropic etch process can be performed to remove horizontalportions of the semiconductor channel material layer and the gatedielectric layer. A terminal step of the anisotropic etch process canetch physically exposed portions of the insulating cap layer 70 suchthat each cavity laterally surrounded by remaining portions of the gatedielectric layer and the semiconductor channel material layer extends toa top surface of a respective underlying connection channel portion 602.Each remaining cylindrical portion of the gate dielectric layerconstitutes a gate dielectric 150. Each remaining cylindrical portion ofthe semiconductor channel material layer constitutes a portion of asemiconductor channel located at the drain select level, which is hereinreferred to as an outer drain-select-level channel portion 604.

Referring to FIG. 50, the processing steps of FIGS. 36A and 36B can beperformed to form a drain-select-level memory opening fill structure(150, 604, 603, 162, 63) within each drain-select-level memory opening.In one embodiment, each of the drain-select-level memory opening fillstructures (150, 604, 603, 162, 63) comprises a drain-select-levelsemiconductor channel portion 603 contacting a top surfaces of arespective one of the connection channel portions 602 and contacting arespective one of the drain regions 63. Each drain region 63 can beformed directly on a top end of a respective one of thedrain-select-level semiconductor channel portions 603. In oneembodiment, top surfaces of the drain regions 63 can be coplanar with atop surface of the drain-select-level insulating layer 132.

Each contiguous combination of a word-line-level semiconductor channelportion 601, a connection channel portion 602 contacting a top end ofthe word-line-level semiconductor channel 601, a drain-select-levelsemiconductor channel portion 603, and an optional outerdrain-select-level channel portion 604 (if present) constitutes avertical semiconductor channel 60. Each contiguous combination of avertical semiconductor channel 60 and a memory film 50 constitutes amemory stack structure 55. A vertical layer stack including aninsulating cap layer 70, drain select electrodes 446, and adrain-select-level insulating layer 132 laterally surrounds atwo-dimensional array of drain-select-level memory opening fillstructures (150, 604, 603, 162, 63). The drain select electrodes 446 arelaterally spaced apart from each other by the drain-select-levelisolation structures 80S.

The drain-select-level memory opening fill structures (150, 604, 603,162, 63) are formed on-pitch with the underlying word-line-levelsemiconductor channel portion 601 and the connection channel portion602. Furthermore, the drain-select-level isolation structures 80S arelocated in a space between rows of adjacent drain-select-level memoryopening fill structures (150, 604, 603, 162, 63). Therefore, thedrain-select-level isolation structures 80S do not extend throughinactive (i.e., dummy) drain-select-level memory opening fillstructures, and the dummy drain-select-level memory opening fillstructures are not required. These features increase the active devicedensity and lowers the chip size and the cost of the device per unitarea. Furthermore, the drain select electrode 446 height may be easilyadjusted by selecting a desired thickness for layer 446L, withoutintroducing voids. Finally, the fabrication method is relatively simpleand reduces the difficulty of the etching steps of prior art methods.

A dielectric cap layer 270 can be subsequently formed over thetwo-dimensional array of drain-select-level memory opening fillstructures (150, 604, 603, 162, 63). The dielectric cap layer 270 canhave the same material composition and the same thickness range as thefirst dielectric cap layer 270 described above.

Referring to FIG. 51, backside trenches can be formed through thedielectric cap layer 270, the drain-select-level insulating spacers 376,the insulating cap layer 70, and the alternating stack of the insulatinglayers 32 and word-line-level sacrificial material layers 42. Thepattern of the backside trenches can be the same as the pattern of thebackside trenches 79 described above.

The processing steps of FIGS. 9A and 9B, 10A and 10B, and 11A and 11Bcan be performed to replace the word-line-level sacrificial materiallayers 42 with word-line-level electrically conductive layers (e.g.,word lines and source select electrodes) 46, and to form dielectricdivider structures 76 in the backside trenches. The dielectric dividerstructures 76 may comprise backside trench fill structures including,and/or consisting essentially of, at least one dielectric material, suchas silicon oxide.

In one embodiment, each of the insulating layers 32 and each of theword-line-level electrically conductive layers 46 within an alternatingstack (32, 46) laterally extend between, and contact sidewalls of, apair of dielectric divider structures 76. In one embodiment, the memorystack structures 55 can be arranged in rows that laterally extend alonga first horizontal direction (e.g., the word line direction, in the samemanner as in the first, second, and third exemplary structures), andeach of the drain-select-level isolation structures 80S laterallyextends along the first horizontal direction and comprises a laterallyalternating sequence of concave vertical sidewall segments and planarvertical sidewall segments.

In one embodiment, a dielectric cap layer 270 overlies the verticallayer stack including the insulating cap layer 70, drain selectelectrodes 446, and the drain-select-level insulating layer 132. Topsurfaces of the pair of dielectric divider structures 76 can be coplanarwith the top surface of the dielectric cap layer 270. In one embodiment,drain-select-level insulating spacers 376 can contact sidewalls of thedielectric divider structure 76 and a bottom surface of the dielectriccap layer 270.

In one embodiment, each of the drain-select-level semiconductor channelportions 603 can be laterally surrounded by a respective gate dielectric150 having a respective cylindrical shape, and can contact theinsulating cap layer 70, a respective one of the drain select electrodes446, and the drain-select-level insulating layer 132. In one embodiment,each of the drain-select-level semiconductor channel portions 603 cancontact a respective cylindrical surface of the insulating cap layer 70.In one embodiment, each of the gate dielectrics 150 comprises an annularbottom surface and a lower portion of an outer sidewall that contact theinsulating cap layer 70.

In one embodiment, the drain select electrodes 446 comprise, and/orconsist essentially of, a doped semiconductor material having a p-typedoping or an n-type doping. Alternatively, the drain select electrodes446 consist essentially of at least one metallic material. In oneembodiment, the insulating cap layer 70 contacts an annular top surfaceof each of the connection channel portions 602.

Referring to FIG. 52, a fifth exemplary structure according to a fifthembodiment of the present disclosure is illustrated. The fifth exemplarystructure can be derived from the third exemplary structure illustratedin FIGS. 28A and 28B by forming a vertical layer stack including aninsulating cap layer 70 and drain-select-level material layers (346S,343, 345). Generally, an alternating stack of inter-word-line insulatinglayers 32 and word-line-level sacrificial material layers 42 can beformed over a substrate. Memory openings 49 can be formed through thealternating stack (32, 42). Memory opening fill structures (50, 601,602, 62) can be formed in the memory openings 49. Each of the memoryopening fill structures (50, 601, 602, 62) comprises a memory film 50, aword-line-level semiconductor channel portion 601, and a connectionchannel portion 602. The vertical layer stack (70, 346S, 343, 345)including an insulating cap layer 70 and the drain-select-level materiallayers (346S, 343, 345) can be formed over the alternating stack and thememory opening fill structures (50, 601, 602, 62).

According to the fifth embodiment of the present disclosure, thedrain-select-level material layers (346S, 343, 345) can include ametallic seed layer 346S, an optional sacrificial liner 343, and adrain-select-level sacrificial material layer 345. The metallic seedlayer 346S includes a metallic material that can function as a seedlayer for subsequent selective deposition of a metallic material. Forexample, the metallic seed layer 346S can include TiN, TaN, WN, Ti, Ta,and/or W. The thickness of the metallic seed layer 346S can be in arange from 3 nm to 60 nm, although lesser and greater thicknesses mayalso be employed. The sacrificial liner 343, if present, includes asacrificial material, such as silicon oxide. The thickness of thesacrificial liner 343 may be in a range from 3 nm to 60 nm, althoughlesser and greater thicknesses may also be employed. Thedrain-select-level sacrificial material layer 345 includes a sacrificialmaterial, such as silicon nitride. The thickness of thedrain-select-level sacrificial material layer 345 may be in a range from60 nm to 1,000 nm, although lesser and greater thicknesses may also beemployed.

Referring to FIG. 53, drain-select-level isolation structures 80S anddrain-select-level insulating spacers 376 can be formed through thedrain-select-level material layers (346S, 343, 345). The pattern of thedrain-select-level isolation structures 80S can be the same as thepattern of the drain-select-level isolation structures 80S in thepreviously described embodiments. The pattern of the drain-select-levelinsulating spacers 376 can be the same as the pattern of thedrain-select-level divider trench 279 that are described above.

The drain-select-level isolation structures 80S and drain-select-levelinsulating spacers 376 can be formed by applying a photoresist layerover the drain-select-level sacrificial material layer 345,lithographically patterning the photoresist layer to form openings thatlaterally extend along a first horizontal direction (which can be thesame as the first horizontal direction illustrated in FIG. 39A), formingline trenches through the drain-select-level material layers (346S, 343,345), removing the photoresist layer, and filling the line trenches witha dielectric fill material, such as silicon oxide.

Referring to FIG. 54, drain-select-level memory openings 149 can beformed through the drain-select-level sacrificial material layer 345,the sacrificial liner 343, and the metallic seed layer 346S over arespective one of the memory opening fill structures (50, 601, 602, 62).The pattern of the drain-select-level memory openings 149 may be thesame as the pattern of the drain-select-level memory openings 149illustrated in FIGS. 33A and 33B.

Referring to FIG. 55, a sacrificial material liner 137 can be optionallyformed by conformal deposition of a first sacrificial material. In oneembodiment, the sacrificial material liner 137 may include asilicon-oxide based dielectric material such as a doped silicate glass(e.g., borosilicate glass) or undoped silicate glass. The thickness ofthe sacrificial material liner 137 may be in a range from 3 nm to 30 nm,although lesser and greater thicknesses may also be employed.

Referring to FIG. 56, a sacrificial fill material layer 139L can bedeposited over the sacrificial material liner 137. Thedrain-select-level memory openings 149 can be filled with thecombination of the sacrificial material liner 137 and the sacrificialfill material layer 139L. In one embodiment, the sacrificial fillmaterial layer 139L may include a semiconductor material (such asamorphous silicon or polysilicon) or a carbon-based material (such asamorphous carbon or diamond-like carbon (DLC)). The sacrificial fillmaterial layer 139L may be deposited by a conformal deposition process.

Referring to FIG. 57, a recess etch process may be performed tovertically recess the material of the sacrificial fill material layer139L selective to the material of the sacrificial material liner 137.The recess etch process may employ an isotropic etch process or ananisotropic etch process. Each remaining portion of the sacrificial fillmaterial layer 139L located in a respective drain-select-level memoryopening 149 constitutes a sacrificial fill material portion 139.

Referring to FIG. 58, a sacrificial capping layer 135L can be optionallydeposited over the sacrificial fill material portions 139 and thesacrificial material liner 137. The sacrificial capping layer 135Lincludes a sacrificial material such as undoped silicate glass or adoped silicate glass.

Referring to FIG. 59, a first planarization process can be performed toremove horizontally-extending portions of the sacrificial capping layer135L and the sacrificial material liner 137 that overlies a horizontalplane including the top surface of the drain-select-level sacrificialmaterial layer 345. Each remaining portion of the sacrificial cappinglayer 135L comprises a sacrificial capping material portion 135.

Referring to FIG. 60, drain-select-level cavities can be formed byremoving the drain-select-level sacrificial material layer 345 and thesacrificial liner 343 selective to the sacrificial capping materialportions 135, the sacrificial material liner 137, the metallic seedlayers 346S, the drain-select-level isolation structures 80S, and thedrain-select-level insulating spacers 376. In one embodiment, thedrain-select-level sacrificial material layer 345 may comprise siliconnitride and the sacrificial liner 343 may comprise silicon oxide. Inthis case, the drain-select-level sacrificial material layer 345 can beremoved by performing a wet etch process employing hot phosphoric acid.The sacrificial liner 343 can be subsequently removed, for example, byan isotropic etch employing dilute hydrofluoric acid.

Referring to FIG. 61, a selective metal deposition process can beperformed to grow a metallic material from the physically exposedsurfaces of the metallic seed layers 346S without growing the metallicmaterial from physically exposed dielectric surfaces. Drain selectelectrodes 346 are formed by vertical growth of the metallic material.Each drain select electrode 346 can include a metallic seed layer 346Sand a metallic material that grows from the top surface of the metallicseed layer 346S. The thickness of each drain select electrode 346 may bein a range from 60 nm to 600 nm, although lesser and greater thicknessesmay also be employed. In an illustrative example, the metallic seedlayer 346S can include a metallic nitride material such as TiN, TaN,and/or WN or an elemental metal, such as Ti, Ta or W, and an upperportion of each drain select electrode 346 can include an elementalmetal such as W, Mo, Co, Ru, or Cu. Generally, the drain selectelectrodes 346 can be formed by selectively growing a metallic materialfrom physically exposed surfaces of the metallic seed layer 346S whilesuppressing growth of the metallic material from dielectric surfaces.

Generally, drain select electrodes 346 and drain-select-level isolationstructures 80S can be formed by patterning and/or replacing portions ofthe vertical layer stack (70, 346S, 343, 345) including an insulatingcap layer 70 and the drain-select-level material layers (346S, 343, 345)as formed at the processing steps of FIG. 52. The drain selectelectrodes 346 are laterally spaced apart from each other by thedrain-select-level isolation structures 80S.

Referring to FIG. 62, a drain-select-level insulating layer 132 can bedeposited over the drain select electrodes 346, the sacrificial cappingmaterial portions 135, and the sacrificial material liner 137. Thedrain-select-level insulating layer 132 includes a dielectric material,such as silicon oxide.

Referring to FIG. 63, a second planarization process can be performed toremove material portions located above a horizontal plane including topsurfaces of the sacrificial fill material portions 139. A chemicalmechanical planarization process and/or a recess etch process may beperformed to effect the second planarization process.

Referring to FIG. 64, the sacrificial fill material portions 139 can beremoved selective to the materials of the drain-select-level insulatinglayer 132, the drain-select-level isolation structures 80S, and thedrain-select-level insulating spacers 376. In case the sacrificial fillmaterial portions 139 include a semiconductor material (such aspolysilicon or amorphous silicon), a wet etch process employing hottrimethyl-2 hydroxyethyl ammonium hydroxide (“hot TMY”) or tetramethylammonium hydroxide (TMAH) may be performed to remove the sacrificialfill material portions 139 selective to the materials of thedrain-select-level insulating layer 132, the drain-select-levelisolation structures 80S, and the drain-select-level insulating spacers376. Voids are formed in the volumes of the drain-select-level memoryopenings 149.

Referring to FIG. 65, the processing steps of FIG. 49 may be performed.Specifically, a gate dielectric layer can be formed by conformaldeposition of a gate dielectric material. The gate dielectric layer canhave the same material composition and the same thickness as the gatedielectrics 150 described above. Optionally, a semiconductor channelmaterial layer can be deposited over the gate dielectric layer.

An anisotropic etch process can be performed to remove horizontalportions of the semiconductor channel material layer and the gatedielectric layer. A terminal step of the anisotropic etch process canetch physically exposed portions of the insulating cap layer 70 suchthat each cavity laterally surrounded by remaining portions of the gatedielectric layer and the semiconductor channel material layer extends toa top surface of a respective underlying connection channel portion 602.Each remaining cylindrical portion of the gate dielectric layerconstitutes a gate dielectric 150. Each remaining cylindrical portion ofthe semiconductor channel material layer constitutes a portion of asemiconductor channel located at the drain select level, which is hereinreferred to as an outer drain-select-level channel portion 604.

Referring to FIG. 66, the processing steps of FIGS. 36A and 36B can beperformed to form a drain-select-level memory opening fill structure(150, 604, 603, 162, 63) within each drain-select-level memory opening149. In one embodiment, each of the drain-select-level memory openingfill structures (150, 604, 603, 162, 63) comprises a drain-select-levelsemiconductor channel portion 603 contacting a top surfaces of arespective one of the connection channel portions 602 and contacting arespective one of the drain regions 63. Each drain region 63 can beformed directly on a top end of a respective one of thedrain-select-level semiconductor channel portions 603. In oneembodiment, top surfaces of the drain regions 63 can be coplanar with atop surface of the drain-select-level insulating layer 132.

Each contiguous combination of a word-line-level semiconductor channelportion 601, a connection channel portion 602 contacting a top end ofthe word-line-level semiconductor channel 601, a drain-select-levelsemiconductor channel portion 603, and an optional outerdrain-select-level channel portion 604 (if present) constitutes avertical semiconductor channel 60. Each contiguous combination of avertical semiconductor channel 60 and a memory film 50 constitutes amemory stack structure 55. A vertical layer stack including aninsulating cap layer 70, drain select electrodes 346, and adrain-select-level insulating layer 132 laterally surrounds atwo-dimensional array of drain-select-level memory opening fillstructures (150, 604, 603, 162, 63). The drain select electrodes 346 arelaterally spaced apart from each other by the drain-select-levelisolation structures 80S. A dielectric cap layer 270 can be subsequentlyformed over the two-dimensional array of drain-select-level memoryopening fill structures (150, 604, 603, 162, 63). The dielectric caplayer 270 can have the same material composition and the same thicknessrange as the first dielectric cap layer 270 described above.

Referring to FIG. 67, backside trenches can be formed through thedielectric cap layer 270, the drain-select-level insulating spacers 376,the insulating cap layer 70, and the alternating stack of the insulatinglayers 32 and word-line-level sacrificial material layers 42. Thepattern of the backside trenches can be the same as the pattern of thebackside trenches 79 described above.

The processing steps of FIGS. 9A and 9B, 10A and 10B, and 11A and 11Bcan be performed to replace the word-line-level sacrificial materiallayers 42 with word-line-level electrically conductive layers (e.g.,word lines and source select electrodes) 46, and to form dielectricdivider structures 76 in the backside trenches. The backside trench fillstructures 76 may include and/or consist essentially of at least onedielectric material, such as silicon oxide.

The method of the fifth embodiment is simplified because an etch stoplayer may be omitted. Furthermore, the device of the fifth embodimenthas an improved cell current due to the short distance between the drainselect electrodes 346 and the topmost word line 46, since there is noetch stop layer located between them.

Referring to all drawings and according to various embodiments of thepresent disclosure, a three-dimensional memory device comprises analternating stack of insulating layers 32 and word-line-levelelectrically conductive layers 46 located over a substrate; a verticallayer stack located over the alternating stack, the vertical layer stackincluding an insulating cap layer 70, drain select electrodes (346,446), and a drain-select-level insulating layer 132, wherein the drainselect electrodes (346, 446) are laterally spaced apart from each otherby drain-select-level isolation structures 80S; and memory stackstructures 55 comprising a respective vertical semiconductor channel 60and a respective memory film 50 vertically extending through thealternating stack (32, 46) and the vertical layer stack (70, 346 or 446,132), wherein each of the vertical semiconductor channels 60 comprises aword-line-level semiconductor channel portion 601 extending through thealternating stack (32, 46), a connection channel portion 602 contactinga top end of the word-line-level semiconductor channel 601, and adrain-select-level semiconductor channel portion 603 verticallyextending through the vertical layer stack (70, 346 or 446, 132).

In one embodiment, the three-dimensional memory device comprises drainregions 63 contacting a top end of a respective one of thedrain-select-level semiconductor channel portions 603. In oneembodiment, top surfaces of the drain regions 63 are coplanar with a topsurface of the drain-select-level insulating layer 132.

In one embodiment, each of the insulating layers 32 and each of theword-line-level electrically conductive layers 46 within an alternatingstack (32, 46) laterally extend between, and contact sidewalls of, apair of dielectric divider structures 76. In one embodiment, the memorystack structures 55 can be arranged in rows that laterally extend alonga first horizontal direction (in the same manner as in the first,second, and third exemplary structures), and each of thedrain-select-level isolation structures 80S laterally extends along thefirst horizontal direction and comprises a laterally alternatingsequence of concave vertical sidewall segments and planar verticalsidewall segments.

In one embodiment, a dielectric cap layer 270 overlies the verticallayer stack including the insulating cap layer 70, drain selectelectrodes (346, 446), and the drain-select-level insulating layer 132.Top surfaces of the pair of dielectric divider structures 76 can becoplanar with the top surface of the dielectric cap layer 270. In oneembodiment, drain-select-level insulating spacers 376 can contact asidewall of a respective one of the pair of dielectric dividerstructures 376 and a bottom surface of the dielectric cap layer 270.

In one embodiment, each of the drain-select-level semiconductor channelportions 603 can be laterally surrounded by a respective gate dielectric150 having a respective cylindrical shape, and can contact theinsulating cap layer 70, a respective one of the drain select electrodes(346, 446), and the drain-select-level insulating layer 132. In oneembodiment, each of the drain-select-level semiconductor channelportions 603 can contact a respective cylindrical surface of theinsulating cap layer 70. In one embodiment, each of the gate dielectrics150 comprises an annular bottom surface and a lower portion of an outersidewall that contact the insulating cap layer 70.

In one embodiment, the drain select electrodes 446 comprise, and/orconsist essentially of, a doped semiconductor material having a p-typedoping or an n-type doping. Alternatively, the drain select electrodes(346 or 446) consist essentially of at least one metallic material. Inone embodiment, the insulating cap layer 70 contacts an annular topsurface of each of the connection channel portions 602.

The various embodiments of the present disclosure may be employed toprovide an on-pitch two-dimensional periodic array of memory openingfill structures (50, 601, 602, 62) and an on-pitch two-dimensionalperiodic array of drain-select-level memory opening fill structures(150, 604, 603, 162, 63) that are located between a neighboring pair ofdielectric divider structures 76. Dummy memory opening fill structurescan be eliminated, and a three-dimensional memory array having a higherdevice density can be provided.

Although the foregoing refers to particular preferred embodiments, itwill be understood that the disclosure is not so limited. It will occurto those of ordinary skill in the art that various modifications may bemade to the disclosed embodiments and that such modifications areintended to be within the scope of the disclosure. Compatibility ispresumed among all embodiments that are not alternatives of one another.The word “comprise” or “include” contemplates all embodiments in whichthe word “consist essentially of” or the word “consists of” replaces theword “comprise” or “include,” unless explicitly stated otherwise. Wherean embodiment employing a particular structure and/or configuration isillustrated in the present disclosure, it is understood that the presentdisclosure may be practiced with any other compatible structures and/orconfigurations that are functionally equivalent provided that suchsubstitutions are not explicitly forbidden or otherwise known to beimpossible to one of ordinary skill in the art. All of the publications,patent applications and patents cited herein are incorporated herein byreference in their entirety.

What is claimed is:
 1. A three-dimensional memory device, comprising: analternating stack of insulating layers and word-line-level electricallyconductive layers located over a substrate; a vertical layer stacklocated over the alternating stack, the vertical layer stack comprisingan insulating cap layer, drain select electrodes, and adrain-select-level insulating layer, wherein the drain select electrodesare laterally spaced apart from each other by drain-select-levelisolation structures; and memory stack structures comprising arespective vertical semiconductor channel and a respective memory filmvertically extending through the alternating stack and the verticallayer stack, wherein each of the vertical semiconductor channelscomprises a word-line-level semiconductor channel portion extendingthrough the alternating stack, a connection channel portion contacting atop end of the word-line-level semiconductor channel, and adrain-select-level semiconductor channel portion vertically extendingthrough the vertical layer stack.
 2. The three-dimensional memory deviceof claim 1, further comprising drain regions contacting a top end of arespective one of the drain-select-level semiconductor channel portions.3. The three-dimensional memory device of claim 2, wherein top surfacesof the drain regions are coplanar with a top surface of thedrain-select-level insulating layer.
 4. The three-dimensional memorydevice of claim 1, wherein each of the insulating layers and each of theword-line-level electrically conductive layers laterally extend betweenand contact sidewalls of a pair of dielectric divider structures.
 5. Thethree-dimensional memory device of claim 4, wherein: the memory stackstructures are arranged in rows that laterally extend along a firsthorizontal direction; and each of the drain-select-level isolationstructures laterally extends along the first horizontal direction andcomprises a laterally alternating sequence of concave vertical sidewallsegments and planar vertical sidewall segments.
 6. The three-dimensionalmemory device of claim 4, further comprising a dielectric cap layeroverlying the vertical layer stack, wherein top surfaces of the pair ofdielectric divider structures are coplanar with a top surface of thedielectric cap layer.
 7. The three-dimensional memory device of claim 6,further comprising drain-select-level insulating spacers contacting asidewall of a respective one of the pair of dielectric dividerstructures and a bottom surface of the dielectric cap layer.
 8. Thethree-dimensional memory device of claim 1, wherein each of thedrain-select-level semiconductor channel portions is laterallysurrounded by a respective gate dielectric having a respectivecylindrical shape and contacting the insulating cap layer, a respectiveone of the drain select electrodes, and the drain-select-levelinsulating layer.
 9. The three-dimensional memory device of claim 8,wherein each of the drain-select-level semiconductor channel portionscontacts a respective cylindrical surface of the insulating cap layer.10. The three-dimensional memory device of claim 8, wherein each of thegate dielectrics comprises an annular bottom surface and a lower portionof an outer sidewall that contact the insulating cap layer.
 11. Thethree-dimensional memory device of claim 1, wherein the drain selectelectrodes comprise a doped semiconductor material having a p-typedoping or an n-type doping.
 12. The three-dimensional memory device ofclaim 1, wherein the drain select electrodes consist essentially of atleast one metallic material.
 13. The three-dimensional memory device ofclaim 1, wherein the insulating cap layer contacts an annular topsurface of each of the connection channel portions.
 14. A method offorming a three-dimensional memory device, comprising: forming analternating stack of inter-word-line insulating layers andword-line-level sacrificial material layers over a substrate; formingmemory openings through the alternating stack; forming memory openingfill structures in the memory openings, wherein each of the memoryopening fill structures comprises a memory film, a word-line-levelsemiconductor channel portion, and a connection channel portion; forminga vertical layer stack including an insulating cap layer anddrain-select-level material layers over the alternating stack and thememory opening fill structures; forming drain select electrodes anddrain-select-level isolation structures by patterning or replacingportions of the vertical layer stack, wherein the drain selectelectrodes are laterally spaced apart from each other bydrain-select-level isolation structures; forming backside trenchesthrough the vertical layer stack and the alternating stack; andreplacing the word-line-level sacrificial material layers withword-line-level electrically conductive layers after formation of thedrain select electrodes and the drain-select-level insulating layer. 15.The method of claim 14, wherein: the drain-select-level material layerscomprise a metallic seed layer and a drain-select-level sacrificialmaterial layer; and the drain-select-level isolation structures areformed by replacing laterally-extending portions of the vertical layerstack with insulating material portions.
 16. The method of claim 15,wherein the drain select electrodes are formed by selectively growing ametallic material from physically exposed surfaces of the metallic seedlayer while suppressing growth of the metallic material from dielectricsurfaces.
 17. The method of claim 15, further comprising: formingdrain-select-level memory openings through the drain-select-levelmaterial layers and the drain-select-level isolation structures over arespective one of the memory opening fill structures; and formingdrain-select-level memory opening fill structures in thedrain-select-level memory openings, wherein each of thedrain-select-level memory opening fill structures comprises a respectivedrain region.
 18. The method of claim 14, further comprising: formingdrain-select-level memory openings through the drain select electrodesover a respective one of the memory opening fill structures; and formingdrain-select-level memory opening fill structures in thedrain-select-level memory openings, wherein each of thedrain-select-level memory opening fill structures comprises a respectivedrain region.
 19. The method of claim 18, wherein each of thedrain-select-level memory opening fill structures comprises adrain-select-level semiconductor channel portion contacting a topsurface of a respective one of the connection channel portions andcontacting a respective one of the drain regions.
 20. The method ofclaim 18, wherein: the drain-select-level material layers comprise adrain select electrode layer and a drain-select-level insulating layer;the drain-select-level isolation structures are formed through thedrain-select-level insulating layer and the drain select electrodelayer, wherein patterned portions of the drain select electrode layercomprise the drain select electrodes; and the drain-select-level memoryopenings are formed through the drain select electrodes and thedrain-select-level insulating layer.